Visible-Light-Induced sp3C–H Functionalization of Alkyl Amines toward Tetrahydroquinoline Spiro[5.6] Compounds

Peng He; Yakun Jiang; Zongkang Wang; Nana Fei; Yan Wang; Lingkai Kong; Yanzhong Li

doi:10.1021/acs.orglett.5c01130

Visible-Light-Induced sp³C–H Functionalization of Alkyl Amines toward Tetrahydroquinoline Spiro[5.6] Compounds

Peng He
, Yakun Jiang
, Zongkang Wang
, Nana Fei
, Yan Wang
, Lingkai Kong^*
, Yanzhong Li^*

^*此作品的通讯作者

化学与分子工程学院

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

An efficient and green methodology for the synthesis of tetrahydroquinoline spiro[5.6] compounds by visible-light-induced sp³C–H functionalization reactions of alkyl amines has been developed. The advantages of this protocol include inexpensive photocatalysts, high diastereoselectivity, transition-metal-free properties, and wide-scope substrates.

源语言	英语
页（从-至）	9843-9848
页数	6
期刊	Organic Letters
卷	27
期	36
DOI	https://doi.org/10.1021/acs.orglett.5c01130
出版状态	已出版 - 12 9月 2025

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10.1021/acs.orglett.5c01130

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abstract = "An efficient and green methodology for the synthesis of tetrahydroquinoline spiro[5.6] compounds by visible-light-induced sp3C–H functionalization reactions of alkyl amines has been developed. The advantages of this protocol include inexpensive photocatalysts, high diastereoselectivity, transition-metal-free properties, and wide-scope substrates.",

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AU - He, Peng

AU - Jiang, Yakun

AU - Wang, Zongkang

AU - Fei, Nana

AU - Wang, Yan

AU - Kong, Lingkai

AU - Li, Yanzhong

PY - 2025/9/12

Y1 - 2025/9/12

N2 - An efficient and green methodology for the synthesis of tetrahydroquinoline spiro[5.6] compounds by visible-light-induced sp3C–H functionalization reactions of alkyl amines has been developed. The advantages of this protocol include inexpensive photocatalysts, high diastereoselectivity, transition-metal-free properties, and wide-scope substrates.

AB - An efficient and green methodology for the synthesis of tetrahydroquinoline spiro[5.6] compounds by visible-light-induced sp3C–H functionalization reactions of alkyl amines has been developed. The advantages of this protocol include inexpensive photocatalysts, high diastereoselectivity, transition-metal-free properties, and wide-scope substrates.

UR - https://www.scopus.com/pages/publications/105015864734

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M3 - 文章

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AN - SCOPUS:105015864734

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JO - Organic Letters

JF - Organic Letters

IS - 36

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Visible-Light-Induced sp3C–H Functionalization of Alkyl Amines toward Tetrahydroquinoline Spiro[5.6] Compounds

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Visible-Light-Induced sp³C–H Functionalization of Alkyl Amines toward Tetrahydroquinoline Spiro[5.6] Compounds