Visible-Light-Induced NaI-Catalyzed α-C–H Sulfenylation Enables the Synthesis of o-Sulfanylarylamines

Xiaoming Zhu; Jiahong Li; Zheyu Deng; Jiaolong Meng; Jianxin Tang; Xia He; Yuming Nie; Xinbo Hou; Fuxing Zhang; Xuefeng Jiang

doi:10.1021/acs.orglett.6c01487

Visible-Light-Induced NaI-Catalyzed α-C–H Sulfenylation Enables the Synthesis of o-Sulfanylarylamines

Xiaoming Zhu^*
, Jiahong Li
, Zheyu Deng
, Jiaolong Meng
, Jianxin Tang
, Xia He
, Yuming Nie
, Xinbo Hou
, Fuxing Zhang
, Xuefeng Jiang^*

^*此作品的通讯作者

化学与分子工程学院

Hengyang Normal University
East China Normal University

科研成果: 期刊稿件 › 快报 › 同行评审

摘要

A novel, atom-economical, and environmentally friendly method for the synthesis of o-sulfanylarylamines from arylamines and diaryl disulfides has been developed by constructing C–S bonds from C–H bonds under visible-light irradiation in the absence of transition metals, additives, and photosensitizers. This reaction exhibited a broad substrate scope and excellent functional group compatibility. Furthermore, the efficiency of the continuous flow process demonstrated the potential of the protocol for practical industrial applications.

源语言	英语
页（从-至）	6139-6145
页数	7
期刊	Organic Letters
卷	28
期	19
DOI	https://doi.org/10.1021/acs.orglett.6c01487
出版状态	已出版 - 15 5月 2026

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title = "Visible-Light-Induced NaI-Catalyzed α-C{\textendash}H Sulfenylation Enables the Synthesis of o-Sulfanylarylamines",

abstract = "A novel, atom-economical, and environmentally friendly method for the synthesis of o-sulfanylarylamines from arylamines and diaryl disulfides has been developed by constructing C{\textendash}S bonds from C{\textendash}H bonds under visible-light irradiation in the absence of transition metals, additives, and photosensitizers. This reaction exhibited a broad substrate scope and excellent functional group compatibility. Furthermore, the efficiency of the continuous flow process demonstrated the potential of the protocol for practical industrial applications.",

author = "Xiaoming Zhu and Jiahong Li and Zheyu Deng and Jiaolong Meng and Jianxin Tang and Xia He and Yuming Nie and Xinbo Hou and Fuxing Zhang and Xuefeng Jiang",

note = "Publisher Copyright: {\textcopyright} 2026 American Chemical Society",

year = "2026",

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day = "15",

doi = "10.1021/acs.orglett.6c01487",

language = "英语",

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TY - JOUR

T1 - Visible-Light-Induced NaI-Catalyzed α-C–H Sulfenylation Enables the Synthesis of o-Sulfanylarylamines

AU - Zhu, Xiaoming

AU - Li, Jiahong

AU - Deng, Zheyu

AU - Meng, Jiaolong

AU - Tang, Jianxin

AU - He, Xia

AU - Nie, Yuming

AU - Hou, Xinbo

AU - Zhang, Fuxing

AU - Jiang, Xuefeng

PY - 2026/5/15

Y1 - 2026/5/15

N2 - A novel, atom-economical, and environmentally friendly method for the synthesis of o-sulfanylarylamines from arylamines and diaryl disulfides has been developed by constructing C–S bonds from C–H bonds under visible-light irradiation in the absence of transition metals, additives, and photosensitizers. This reaction exhibited a broad substrate scope and excellent functional group compatibility. Furthermore, the efficiency of the continuous flow process demonstrated the potential of the protocol for practical industrial applications.

AB - A novel, atom-economical, and environmentally friendly method for the synthesis of o-sulfanylarylamines from arylamines and diaryl disulfides has been developed by constructing C–S bonds from C–H bonds under visible-light irradiation in the absence of transition metals, additives, and photosensitizers. This reaction exhibited a broad substrate scope and excellent functional group compatibility. Furthermore, the efficiency of the continuous flow process demonstrated the potential of the protocol for practical industrial applications.

UR - https://www.scopus.com/pages/publications/105038971996

U2 - 10.1021/acs.orglett.6c01487

DO - 10.1021/acs.orglett.6c01487

M3 - 快报

C2 - 42090475

AN - SCOPUS:105038971996

SN - 1523-7060

VL - 28

SP - 6139

EP - 6145

JO - Organic Letters

JF - Organic Letters

IS - 19

ER -

Visible-Light-Induced NaI-Catalyzed α-C–H Sulfenylation Enables the Synthesis of o-Sulfanylarylamines

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