Transition-metal-free aerobic oxidative cleavage of C-C bonds in α-hydroxy ketones and mechanistic insight to the reaction pathway

Hui Liu; Chao Dong; Zeguang Zhang; Peiyu Wu; Xuefeng Jiang

doi:10.1002/anie.201207206

Transition-metal-free aerobic oxidative cleavage of C-C bonds in α-hydroxy ketones and mechanistic insight to the reaction pathway

Hui Liu
, Chao Dong
, Zeguang Zhang
, Peiyu Wu
, Xuefeng Jiang^*

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

129 引用（Scopus）

摘要

Clear cut: For the title reaction, O₂, the ideal oxidant, was used as the only oxidizing reagent. The dimer intermediate (see scheme) and isotopic labeling control experiments with ¹⁸O₂ partially disclosed the reaction mechanism.

源语言	英语
页（从-至）	12570-12574
页数	5
期刊	Angewandte Chemie - International Edition
卷	51
期	50
DOI	https://doi.org/10.1002/anie.201207206
出版状态	已出版 - 7 12月 2012

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10.1002/anie.201207206

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title = "Transition-metal-free aerobic oxidative cleavage of C-C bonds in α-hydroxy ketones and mechanistic insight to the reaction pathway",

abstract = "Clear cut: For the title reaction, O2, the ideal oxidant, was used as the only oxidizing reagent. The dimer intermediate (see scheme) and isotopic labeling control experiments with 18O2 partially disclosed the reaction mechanism.",

keywords = "C-C bond cleavage, esterification, oxidation, synthetic methods, α-hydroxy ketones",

author = "Hui Liu and Chao Dong and Zeguang Zhang and Peiyu Wu and Xuefeng Jiang",

year = "2012",

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T1 - Transition-metal-free aerobic oxidative cleavage of C-C bonds in α-hydroxy ketones and mechanistic insight to the reaction pathway

AU - Liu, Hui

AU - Dong, Chao

AU - Zhang, Zeguang

AU - Wu, Peiyu

AU - Jiang, Xuefeng

PY - 2012/12/7

Y1 - 2012/12/7

N2 - Clear cut: For the title reaction, O2, the ideal oxidant, was used as the only oxidizing reagent. The dimer intermediate (see scheme) and isotopic labeling control experiments with 18O2 partially disclosed the reaction mechanism.

AB - Clear cut: For the title reaction, O2, the ideal oxidant, was used as the only oxidizing reagent. The dimer intermediate (see scheme) and isotopic labeling control experiments with 18O2 partially disclosed the reaction mechanism.

KW - C-C bond cleavage

KW - esterification

KW - oxidation

KW - synthetic methods

KW - α-hydroxy ketones

UR - https://www.scopus.com/pages/publications/84870585765

U2 - 10.1002/anie.201207206

DO - 10.1002/anie.201207206

M3 - 文章

C2 - 23129361

AN - SCOPUS:84870585765

SN - 1433-7851

VL - 51

SP - 12570

EP - 12574

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 50

ER -

Transition-metal-free aerobic oxidative cleavage of C-C bonds in α-hydroxy ketones and mechanistic insight to the reaction pathway

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