Through-space MP-CPMAS experiments between spin-1/2 and half-integer quadrupolar nuclei in solid-state NMR

B. Hu; J. P. Amoureux; J. Trébosc; S. Hafner

doi:10.1016/j.jmr.2008.01.008

Through-space MP-CPMAS experiments between spin-1/2 and half-integer quadrupolar nuclei in solid-state NMR

B. Hu
, J. P. Amoureux^*
, J. Trébosc
, S. Hafner

^*此作品的通讯作者

Université de Lille

科研成果: 期刊稿件 › 文章 › 同行评审

20 引用（Scopus）

摘要

We present a new CPMAS method that allows the acquisition of through-space 2D HETCOR spectra between spin-1/2 nuclei and half-integer quadrupolar nuclei in the solid state. It uses rotor-synchronized selective pulses on the quadrupolar nucleus and continuous-wave RF irradiation on the spin-1/2 nucleus to create hetero-nuclear dipolar coherences. The method is more robust, more efficient, and easier to set up than the standard CPMAS transfer.

源语言	英语
页（从-至）	8-16
页数	9
期刊	Journal of Magnetic Resonance
卷	192
期	1
DOI	https://doi.org/10.1016/j.jmr.2008.01.008
出版状态	已出版 - 5月 2008
已对外发布	是

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title = "Through-space MP-CPMAS experiments between spin-1/2 and half-integer quadrupolar nuclei in solid-state NMR",

abstract = "We present a new CPMAS method that allows the acquisition of through-space 2D HETCOR spectra between spin-1/2 nuclei and half-integer quadrupolar nuclei in the solid state. It uses rotor-synchronized selective pulses on the quadrupolar nucleus and continuous-wave RF irradiation on the spin-1/2 nucleus to create hetero-nuclear dipolar coherences. The method is more robust, more efficient, and easier to set up than the standard CPMAS transfer.",

keywords = "Dipolar coupling, HETCOR, Quadrupolar nuclei, Solid-state NMR",

author = "B. Hu and Amoureux, \{J. P.\} and J. Tr{\'e}bosc and S. Hafner",

year = "2008",

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doi = "10.1016/j.jmr.2008.01.008",

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T1 - Through-space MP-CPMAS experiments between spin-1/2 and half-integer quadrupolar nuclei in solid-state NMR

AU - Hu, B.

AU - Amoureux, J. P.

AU - Trébosc, J.

AU - Hafner, S.

PY - 2008/5

Y1 - 2008/5

N2 - We present a new CPMAS method that allows the acquisition of through-space 2D HETCOR spectra between spin-1/2 nuclei and half-integer quadrupolar nuclei in the solid state. It uses rotor-synchronized selective pulses on the quadrupolar nucleus and continuous-wave RF irradiation on the spin-1/2 nucleus to create hetero-nuclear dipolar coherences. The method is more robust, more efficient, and easier to set up than the standard CPMAS transfer.

AB - We present a new CPMAS method that allows the acquisition of through-space 2D HETCOR spectra between spin-1/2 nuclei and half-integer quadrupolar nuclei in the solid state. It uses rotor-synchronized selective pulses on the quadrupolar nucleus and continuous-wave RF irradiation on the spin-1/2 nucleus to create hetero-nuclear dipolar coherences. The method is more robust, more efficient, and easier to set up than the standard CPMAS transfer.

KW - Dipolar coupling

KW - HETCOR

KW - Quadrupolar nuclei

KW - Solid-state NMR

UR - https://www.scopus.com/pages/publications/42749084823

U2 - 10.1016/j.jmr.2008.01.008

DO - 10.1016/j.jmr.2008.01.008

M3 - 文章

AN - SCOPUS:42749084823

SN - 1090-7807

VL - 192

SP - 8

EP - 16

JO - Journal of Magnetic Resonance

JF - Journal of Magnetic Resonance

IS - 1

ER -

Through-space MP-CPMAS experiments between spin-1/2 and half-integer quadrupolar nuclei in solid-state NMR

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