TY - JOUR
T1 - Synthesis, structure, and photoluminescence of a zinc(II) coordination polymer with 4-(tetrazol-5-yl)benzoate
AU - Zhang, Jian Yong
AU - Wang, Yan Qin
AU - Peng, Hui Qi
AU - Cheng, Ai Ling
AU - Gao, En Qing
PY - 2008/6
Y1 - 2008/6
N2 - A new coordination polymer with interesting supramolecular architecture, [Zn(4-tzbz)] n (1) (4-tzbz = 4-(tetrazol-5-yl)benzoate), has been synthesized and characterized structurally. In this compound, the zinc(II) ions are connected by the tetrazole ring in the μ2-1,4 bridging mode and the carboxylate group in the μ2-1,3 syn-anti bridging mode to generate 2D (4,4) sheets, and the adjacent sheets are linked further by the benzene rings to give the 3D metal-organic framework with a 3,4-connected (83)(84122) topology. This compound in the solid state exhibits photoluminescence assignable to intraligand transitions, and, in particular, the emission at 400 nm is significantly intensified due to the coordination of the ligand to Zn.
AB - A new coordination polymer with interesting supramolecular architecture, [Zn(4-tzbz)] n (1) (4-tzbz = 4-(tetrazol-5-yl)benzoate), has been synthesized and characterized structurally. In this compound, the zinc(II) ions are connected by the tetrazole ring in the μ2-1,4 bridging mode and the carboxylate group in the μ2-1,3 syn-anti bridging mode to generate 2D (4,4) sheets, and the adjacent sheets are linked further by the benzene rings to give the 3D metal-organic framework with a 3,4-connected (83)(84122) topology. This compound in the solid state exhibits photoluminescence assignable to intraligand transitions, and, in particular, the emission at 400 nm is significantly intensified due to the coordination of the ligand to Zn.
KW - Carboxylate
KW - Coordination compounds
KW - Photoluminescence
KW - Tetrazolate
UR - https://www.scopus.com/pages/publications/46649112286
U2 - 10.1007/s11224-008-9314-y
DO - 10.1007/s11224-008-9314-y
M3 - 文章
AN - SCOPUS:46649112286
SN - 1040-0400
VL - 19
SP - 535
EP - 539
JO - Structural Chemistry
JF - Structural Chemistry
IS - 3
ER -