摘要
A new family of 60° dendritic di-Pt(II) acceptor tectons have been successfully designed and synthesized, from which a series of novel "three-component" triangular metallodendrimers were prepared via [3 + 3] coordination-driven self-assembly. The structures of newly designed triangular metallodendrimers are characterized by multinuclear NMR ( 1H and 31P), 1H DOSY NMR, mass spectrometry (CSI-TOF-MS), and elemental analysis. The shape and size of all supramolecular dendritic triangles were investigated with PM6 semiempirical molecular orbital methods.
| 源语言 | 英语 |
|---|---|
| 页(从-至) | 3426-3432 |
| 页数 | 7 |
| 期刊 | Journal of Organic Chemistry |
| 卷 | 77 |
| 期 | 7 |
| DOI | |
| 出版状态 | 已出版 - 6 4月 2012 |
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