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Synthesis of triangular metallodendrimers via coordination-driven self-assembly

  • Qing Han
  • , Li Lei Wang
  • , Quan Jie Li
  • , Guang Zhen Zhao
  • , Jiuming He
  • , Bingjie Hu
  • , Hongwei Tan
  • , Zeper Abliz
  • , Yihua Yu
  • , Hai Bo Yang*
  • *此作品的通讯作者
  • East China Normal University
  • Beijing Normal University
  • Chinese Academy of Medical Sciences

科研成果: 期刊稿件文章同行评审

摘要

A new family of 60° dendritic di-Pt(II) acceptor tectons have been successfully designed and synthesized, from which a series of novel "three-component" triangular metallodendrimers were prepared via [3 + 3] coordination-driven self-assembly. The structures of newly designed triangular metallodendrimers are characterized by multinuclear NMR ( 1H and 31P), 1H DOSY NMR, mass spectrometry (CSI-TOF-MS), and elemental analysis. The shape and size of all supramolecular dendritic triangles were investigated with PM6 semiempirical molecular orbital methods.

源语言英语
页(从-至)3426-3432
页数7
期刊Journal of Organic Chemistry
77
7
DOI
出版状态已出版 - 6 4月 2012

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