Synthesis of Sterically Protected Xanthene Dyes with Bulky Groups at C-3′ and C-7′

Zuhai Lei; Xinran Li; Yi Li; Xiao Luo; Miaomiao Zhou; Youjun Yang

doi:10.1021/acs.joc.5b01746

Synthesis of Sterically Protected Xanthene Dyes with Bulky Groups at C-3′ and C-7′

Zuhai Lei
, Xinran Li
, Yi Li
, Xiao Luo
, Miaomiao Zhou
, Youjun Yang^*

^*此作品的通讯作者

East China University of Science and Technology

科研成果: 期刊稿件 › 文章 › 同行评审

28 引用（Scopus）

摘要

Substitution of the xanthene scaffold with bulky groups at C-3′ and C-7′ is expected to protect the electrophilic central methine carbon against nucleophilic attack and inhibit stacking. However, such structures are not readily prepared via traditional xanthene syntheses. We have devised an alternative and convenient synthesis to enable facile preparation of this subset of xanthene dyes under mild conditions and in good yields.

源语言	英语
页（从-至）	11538-11543
页数	6
期刊	Journal of Organic Chemistry
卷	80
期	22
DOI	https://doi.org/10.1021/acs.joc.5b01746
出版状态	已出版 - 20 11月 2015
已对外发布	是

访问文件

10.1021/acs.joc.5b01746

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{b4c37654e2484f438b4438669a3ece15,

title = "Synthesis of Sterically Protected Xanthene Dyes with Bulky Groups at C-3′ and C-7′",

abstract = "Substitution of the xanthene scaffold with bulky groups at C-3′ and C-7′ is expected to protect the electrophilic central methine carbon against nucleophilic attack and inhibit stacking. However, such structures are not readily prepared via traditional xanthene syntheses. We have devised an alternative and convenient synthesis to enable facile preparation of this subset of xanthene dyes under mild conditions and in good yields.",

author = "Zuhai Lei and Xinran Li and Yi Li and Xiao Luo and Miaomiao Zhou and Youjun Yang",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

month = nov,

day = "20",

doi = "10.1021/acs.joc.5b01746",

language = "英语",

volume = "80",

pages = "11538--11543",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "22",

}

TY - JOUR

T1 - Synthesis of Sterically Protected Xanthene Dyes with Bulky Groups at C-3′ and C-7′

AU - Lei, Zuhai

AU - Li, Xinran

AU - Li, Yi

AU - Luo, Xiao

AU - Zhou, Miaomiao

AU - Yang, Youjun

PY - 2015/11/20

Y1 - 2015/11/20

N2 - Substitution of the xanthene scaffold with bulky groups at C-3′ and C-7′ is expected to protect the electrophilic central methine carbon against nucleophilic attack and inhibit stacking. However, such structures are not readily prepared via traditional xanthene syntheses. We have devised an alternative and convenient synthesis to enable facile preparation of this subset of xanthene dyes under mild conditions and in good yields.

AB - Substitution of the xanthene scaffold with bulky groups at C-3′ and C-7′ is expected to protect the electrophilic central methine carbon against nucleophilic attack and inhibit stacking. However, such structures are not readily prepared via traditional xanthene syntheses. We have devised an alternative and convenient synthesis to enable facile preparation of this subset of xanthene dyes under mild conditions and in good yields.

UR - https://www.scopus.com/pages/publications/84947967599

U2 - 10.1021/acs.joc.5b01746

DO - 10.1021/acs.joc.5b01746

M3 - 文章

AN - SCOPUS:84947967599

SN - 0022-3263

VL - 80

SP - 11538

EP - 11543

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 22

ER -

Synthesis of Sterically Protected Xanthene Dyes with Bulky Groups at C-3′ and C-7′

摘要

访问文件

其它文件与链接

学术指纹

引用此