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Synthesis of platinum acetylide derivatives with different shapes and their gel formation behavior

  • Li Jun Chen
  • , Jing Zhang
  • , Jiuming He
  • , Xing Dong Xu
  • , Nai Wei Wu
  • , De Xian Wang
  • , Zeper Abliz
  • , Hai Bo Yang*
  • *此作品的通讯作者
  • East China Normal University
  • Chinese Academy of Medical Sciences
  • CAS - Institute of Chemistry

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

The synthesis of a series of platinum acetylide derivatives, featuring linear, triangular, and rectangular shapes, respectively, is described. The structures of these complexes were characterized by multinuclear NMR ( 1H, 13C, and 31P), CSI-TOF mass spectrometry, and elemental analysis. It was found that these complexes exhibited unexpectedly different gel formation properties in the most common organic solvents. Moreover, the organometallic gels of C1 and C2 exhibited concentration-and temperature-dependent emission properties.

源语言英语
页(从-至)5590-5594
页数5
期刊Organometallics
卷30
期21
DOI
出版状态已出版 - 14 11月 2011

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