Synthesis of a β-cyclodextrin derivate and its molecular recognition behavior on modified glassy carbon electrode by diazotization

Xiuhua Wang; Hao Fan; Fan Zhang; Yantao Qi; Wenwei Qiu; Fan Yang; Jie Tang; Pingang He

doi:10.1016/j.tet.2010.07.052

Synthesis of a β-cyclodextrin derivate and its molecular recognition behavior on modified glassy carbon electrode by diazotization

Xiuhua Wang
, Hao Fan
, Fan Zhang
, Yantao Qi
, Wenwei Qiu
, Fan Yang
, Jie Tang^*
, Pingang He

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

16 引用（Scopus）

摘要

A novel β-cyclodextrin (β-CD) derivative containing mono-phenylamino (MPA-β-CD) was newly synthesized by classical Mitsunobu reaction in good yield, and its structure has been confirmed by ¹H NMR, ¹³C NMR and electrospray ionization mass spectra. The compound MPA-β-CD was immobilized onto glassy carbon electrode (GCE) by diazotization, and with this modified electrode the binding behavior of MPA-β-CD for ferrocene (Fc) was investigated qualitatively, and the comparison of differential pulse voltammetry before and after immersion in ferrocene solution indicated that the MPA-β-CD immobilized GCE exhibited the molecular recognition behavior between β-CD and ferrocene.

源语言	英语
页（从-至）	7815-7820
页数	6
期刊	Tetrahedron
卷	66
期	39
DOI	https://doi.org/10.1016/j.tet.2010.07.052
出版状态	已出版 - 25 9月 2010

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10.1016/j.tet.2010.07.052

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@article{8875ea415b0a445c908c9bea2b14422c,

title = "Synthesis of a β-cyclodextrin derivate and its molecular recognition behavior on modified glassy carbon electrode by diazotization",

abstract = "A novel β-cyclodextrin (β-CD) derivative containing mono-phenylamino (MPA-β-CD) was newly synthesized by classical Mitsunobu reaction in good yield, and its structure has been confirmed by 1H NMR, 13C NMR and electrospray ionization mass spectra. The compound MPA-β-CD was immobilized onto glassy carbon electrode (GCE) by diazotization, and with this modified electrode the binding behavior of MPA-β-CD for ferrocene (Fc) was investigated qualitatively, and the comparison of differential pulse voltammetry before and after immersion in ferrocene solution indicated that the MPA-β-CD immobilized GCE exhibited the molecular recognition behavior between β-CD and ferrocene.",

keywords = "Cyclodextrins, Diazotization, Ferrocene, Mitsunobu reaction, Molecular recognition",

author = "Xiuhua Wang and Hao Fan and Fan Zhang and Yantao Qi and Wenwei Qiu and Fan Yang and Jie Tang and Pingang He",

year = "2010",

month = sep,

day = "25",

doi = "10.1016/j.tet.2010.07.052",

language = "英语",

volume = "66",

pages = "7815--7820",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier Ltd",

number = "39",

}

TY - JOUR

T1 - Synthesis of a β-cyclodextrin derivate and its molecular recognition behavior on modified glassy carbon electrode by diazotization

AU - Wang, Xiuhua

AU - Fan, Hao

AU - Zhang, Fan

AU - Qi, Yantao

AU - Qiu, Wenwei

AU - Yang, Fan

AU - Tang, Jie

AU - He, Pingang

PY - 2010/9/25

Y1 - 2010/9/25

N2 - A novel β-cyclodextrin (β-CD) derivative containing mono-phenylamino (MPA-β-CD) was newly synthesized by classical Mitsunobu reaction in good yield, and its structure has been confirmed by 1H NMR, 13C NMR and electrospray ionization mass spectra. The compound MPA-β-CD was immobilized onto glassy carbon electrode (GCE) by diazotization, and with this modified electrode the binding behavior of MPA-β-CD for ferrocene (Fc) was investigated qualitatively, and the comparison of differential pulse voltammetry before and after immersion in ferrocene solution indicated that the MPA-β-CD immobilized GCE exhibited the molecular recognition behavior between β-CD and ferrocene.

AB - A novel β-cyclodextrin (β-CD) derivative containing mono-phenylamino (MPA-β-CD) was newly synthesized by classical Mitsunobu reaction in good yield, and its structure has been confirmed by 1H NMR, 13C NMR and electrospray ionization mass spectra. The compound MPA-β-CD was immobilized onto glassy carbon electrode (GCE) by diazotization, and with this modified electrode the binding behavior of MPA-β-CD for ferrocene (Fc) was investigated qualitatively, and the comparison of differential pulse voltammetry before and after immersion in ferrocene solution indicated that the MPA-β-CD immobilized GCE exhibited the molecular recognition behavior between β-CD and ferrocene.

KW - Cyclodextrins

KW - Diazotization

KW - Ferrocene

KW - Mitsunobu reaction

KW - Molecular recognition

UR - https://www.scopus.com/pages/publications/77956393230

U2 - 10.1016/j.tet.2010.07.052

DO - 10.1016/j.tet.2010.07.052

M3 - 文章

AN - SCOPUS:77956393230

SN - 0040-4020

VL - 66

SP - 7815

EP - 7820

JO - Tetrahedron

JF - Tetrahedron

IS - 39

ER -

Synthesis of a β-cyclodextrin derivate and its molecular recognition behavior on modified glassy carbon electrode by diazotization

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