Synthesis and structure of three dichromium hexacarbonyl complexes with (CPPh2)2, (CHPPh2)2, and carbazole bridges

Xiaohui Tian; Haitao Sun; Yizhong Yuan; Jiaping Lin; Lixian Liang; Yanchao Che

doi:10.1016/j.tet.2010.09.058

Synthesis and structure of three dichromium hexacarbonyl complexes with (CPPh₂)₂, (CHPPh₂)₂, and carbazole bridges

Xiaohui Tian^*
, Haitao Sun
, Yizhong Yuan
, Jiaping Lin
, Lixian Liang
, Yanchao Che

^*此作品的通讯作者

Ministry of Education of the People's Republic of China
East China University of Science and Technology

科研成果: 期刊稿件 › 文章 › 同行评审

2 引用（Scopus）

摘要

Three dichromium hexacarbonyl complexes containing (CPPh₂) ₂, (CHPPh₂)₂, and carbazole as a conjugated bridging ligand are synthesized and exhibit a variety of electronic interactions between the metal centers, which can be modified by altering either the conjugated bridging nature or the ligand bound to the metals to induce peculiar asymmetry.

源语言	英语
页（从-至）	9456-9460
页数	5
期刊	Tetrahedron
卷	66
期	48
DOI	https://doi.org/10.1016/j.tet.2010.09.058
出版状态	已出版 - 27 11月 2010
已对外发布	是

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10.1016/j.tet.2010.09.058

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abstract = "Three dichromium hexacarbonyl complexes containing (CPPh2) 2, (CHPPh2)2, and carbazole as a conjugated bridging ligand are synthesized and exhibit a variety of electronic interactions between the metal centers, which can be modified by altering either the conjugated bridging nature or the ligand bound to the metals to induce peculiar asymmetry.",

keywords = "Conjugated bridging ligand, DFT, Dichromium hexacarbonyl complex, Electronic interaction, MLCT",

author = "Xiaohui Tian and Haitao Sun and Yizhong Yuan and Jiaping Lin and Lixian Liang and Yanchao Che",

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AU - Tian, Xiaohui

AU - Sun, Haitao

AU - Yuan, Yizhong

AU - Lin, Jiaping

AU - Liang, Lixian

AU - Che, Yanchao

PY - 2010/11/27

Y1 - 2010/11/27

N2 - Three dichromium hexacarbonyl complexes containing (CPPh2) 2, (CHPPh2)2, and carbazole as a conjugated bridging ligand are synthesized and exhibit a variety of electronic interactions between the metal centers, which can be modified by altering either the conjugated bridging nature or the ligand bound to the metals to induce peculiar asymmetry.

AB - Three dichromium hexacarbonyl complexes containing (CPPh2) 2, (CHPPh2)2, and carbazole as a conjugated bridging ligand are synthesized and exhibit a variety of electronic interactions between the metal centers, which can be modified by altering either the conjugated bridging nature or the ligand bound to the metals to induce peculiar asymmetry.

KW - Conjugated bridging ligand

KW - DFT

KW - Dichromium hexacarbonyl complex

KW - Electronic interaction

KW - MLCT

UR - https://www.scopus.com/pages/publications/78049463053

U2 - 10.1016/j.tet.2010.09.058

DO - 10.1016/j.tet.2010.09.058

M3 - 文章

AN - SCOPUS:78049463053

SN - 0040-4020

VL - 66

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JO - Tetrahedron

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ER -