摘要
N,N′-bis(L-phenylalanyl)ethane-l,2-diamine was prepared by using L-phenylalanine and ethane-diamine. The synthetic process was improved. The ligand reacted with copper dichloride to form the chiral coordination compound. The single crystal was obtained in methanol solution. It is shown by X-ray structural studies that the crystal belongs to the tetragonal system and the space group is I4. The lattice parameters are as follows: a = 2.5044(4) nm, b = 2.5044(4) nm, c = 0.8707(3) nm, V = 5.461(2) nm3, Dc = 1.365 g/ cm3, Z = 8. In the structure of the complex, the Cu(II) cation is coordinated by two nitrogen atoms, two oxygen atoms and one chlorine atom.
| 源语言 | 英语 |
|---|---|
| 页(从-至) | 812-816 |
| 页数 | 5 |
| 期刊 | Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities |
| 卷 | 27 |
| 期 | 5 |
| 出版状态 | 已出版 - 5月 2006 |
指纹
探究 'Synthesis and crystal structure of a tetramer chiral complex {[Cu(C20H26N4O2)Cl] Cl·4H2O}4' 的科研主题。它们共同构成独一无二的指纹。引用此
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