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Synthesis and crystal structure of a tetramer chiral complex {[Cu(C20H26N4O2)Cl] Cl·4H2O}4

  • Yun Fei He*
  • , Min Qin Chen
  • , Li Yi Dai
  • , Gui Rong Zhang
  • , Qiang Li
  • , Lin Sheng Wang
  • *此作品的通讯作者
  • East China Normal University
  • Fudan University

科研成果: 期刊稿件文章同行评审

摘要

N,N′-bis(L-phenylalanyl)ethane-l,2-diamine was prepared by using L-phenylalanine and ethane-diamine. The synthetic process was improved. The ligand reacted with copper dichloride to form the chiral coordination compound. The single crystal was obtained in methanol solution. It is shown by X-ray structural studies that the crystal belongs to the tetragonal system and the space group is I4. The lattice parameters are as follows: a = 2.5044(4) nm, b = 2.5044(4) nm, c = 0.8707(3) nm, V = 5.461(2) nm3, Dc = 1.365 g/ cm3, Z = 8. In the structure of the complex, the Cu(II) cation is coordinated by two nitrogen atoms, two oxygen atoms and one chlorine atom.

源语言英语
页(从-至)812-816
页数5
期刊Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
27
5
出版状态已出版 - 5月 2006

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