TY - JOUR
T1 - Synthesis and characterization of novel mesogen-jacketed liquid crystalline miktoarm star rod-coil block copolymer
AU - Chen, Jianfang
AU - Wang, Xingzhu
AU - Liao, Xiaojuan
AU - Zhang, Hailiang
AU - Wang, Xiayu
AU - Zhou, Qifeng
PY - 2006/1/3
Y1 - 2006/1/3
N2 - A series of novel mesogen-jacketed liquid crystal miktoarm star rod-coil block copolymers were synthesized via atom transfer radical polymerization (ATRP). Their architectures {coil conformation of styrene segment and rigid rod conformation of {2,5-bis[(4-methoxyphenyl)oxycarbonyljstyrene) (MFCS) segment} were confirmed by OPC, 1H NMR, and MALDI-TOF studies. The liquid crystalline behaviors of the synthesized copolymers are evidenced from POM observation. The liquid crystalline phase depends on the molecular weights of the rigid rod arm of miktoarm star copolymers.
AB - A series of novel mesogen-jacketed liquid crystal miktoarm star rod-coil block copolymers were synthesized via atom transfer radical polymerization (ATRP). Their architectures {coil conformation of styrene segment and rigid rod conformation of {2,5-bis[(4-methoxyphenyl)oxycarbonyljstyrene) (MFCS) segment} were confirmed by OPC, 1H NMR, and MALDI-TOF studies. The liquid crystalline behaviors of the synthesized copolymers are evidenced from POM observation. The liquid crystalline phase depends on the molecular weights of the rigid rod arm of miktoarm star copolymers.
KW - Atom transfer radical polymerization (ATRP)
KW - Mesogen-jacketed liquid crystal polymer
KW - Miktoarm star copolymer
KW - Rod-coil block copolymer
UR - https://www.scopus.com/pages/publications/30444446965
U2 - 10.1002/marc.200500605
DO - 10.1002/marc.200500605
M3 - 文章
AN - SCOPUS:30444446965
SN - 1022-1336
VL - 27
SP - 51
EP - 56
JO - Macromolecular Rapid Communications
JF - Macromolecular Rapid Communications
IS - 1
ER -