Synthesis and characterization of a multimode stationary phase: Congo red derivatized silica in nano-flow HPLC

Yi Zhang; Yan Zhang; Guan Wang; Wujuan Chen; Pingang He; Qingjiang Wang

doi:10.1039/c5an02021b

Synthesis and characterization of a multimode stationary phase: Congo red derivatized silica in nano-flow HPLC

Yi Zhang
, Yan Zhang
, Guan Wang
, Wujuan Chen
, Pingang He
, Qingjiang Wang^*

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

12 引用（Scopus）

摘要

A novel Congo red (CR) derivatized silica stationary phase was prepared and packed into a fused silica capillary tube for nano-flow HPLC. A variety of analytes including poly-aromatic hydrocarbons, parabens, acids, sulfonamides, bases, and nucleosides were successfully separated using the CR. In comparison with commercial ODS columns, this new stationary phase has a different separation mechanism (hydrophobically-assisted ion-exchange), which was evident in the separation of benzoic acid derivatives and sulfonamides. The successful application of CR-bonded silica stationary phase in the HILIC and PALC modes demonstrates the effectiveness of this potential chromatographic material in nano flow HPLC.

源语言	英语
页（从-至）	1083-1090
页数	8
期刊	Analyst
卷	141
期	3
DOI	https://doi.org/10.1039/c5an02021b
出版状态	已出版 - 7 2月 2016

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abstract = "A novel Congo red (CR) derivatized silica stationary phase was prepared and packed into a fused silica capillary tube for nano-flow HPLC. A variety of analytes including poly-aromatic hydrocarbons, parabens, acids, sulfonamides, bases, and nucleosides were successfully separated using the CR. In comparison with commercial ODS columns, this new stationary phase has a different separation mechanism (hydrophobically-assisted ion-exchange), which was evident in the separation of benzoic acid derivatives and sulfonamides. The successful application of CR-bonded silica stationary phase in the HILIC and PALC modes demonstrates the effectiveness of this potential chromatographic material in nano flow HPLC.",

author = "Yi Zhang and Yan Zhang and Guan Wang and Wujuan Chen and Pingang He and Qingjiang Wang",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",

year = "2016",

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doi = "10.1039/c5an02021b",

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TY - JOUR

T1 - Synthesis and characterization of a multimode stationary phase

T2 - Congo red derivatized silica in nano-flow HPLC

AU - Zhang, Yi

AU - Zhang, Yan

AU - Wang, Guan

AU - Chen, Wujuan

AU - He, Pingang

AU - Wang, Qingjiang

PY - 2016/2/7

Y1 - 2016/2/7

N2 - A novel Congo red (CR) derivatized silica stationary phase was prepared and packed into a fused silica capillary tube for nano-flow HPLC. A variety of analytes including poly-aromatic hydrocarbons, parabens, acids, sulfonamides, bases, and nucleosides were successfully separated using the CR. In comparison with commercial ODS columns, this new stationary phase has a different separation mechanism (hydrophobically-assisted ion-exchange), which was evident in the separation of benzoic acid derivatives and sulfonamides. The successful application of CR-bonded silica stationary phase in the HILIC and PALC modes demonstrates the effectiveness of this potential chromatographic material in nano flow HPLC.

AB - A novel Congo red (CR) derivatized silica stationary phase was prepared and packed into a fused silica capillary tube for nano-flow HPLC. A variety of analytes including poly-aromatic hydrocarbons, parabens, acids, sulfonamides, bases, and nucleosides were successfully separated using the CR. In comparison with commercial ODS columns, this new stationary phase has a different separation mechanism (hydrophobically-assisted ion-exchange), which was evident in the separation of benzoic acid derivatives and sulfonamides. The successful application of CR-bonded silica stationary phase in the HILIC and PALC modes demonstrates the effectiveness of this potential chromatographic material in nano flow HPLC.

UR - https://www.scopus.com/pages/publications/84956710831

U2 - 10.1039/c5an02021b

DO - 10.1039/c5an02021b

M3 - 文章

C2 - 26646316

AN - SCOPUS:84956710831

SN - 0003-2654

VL - 141

SP - 1083

EP - 1090

JO - Analyst

JF - Analyst

IS - 3

ER -

Synthesis and characterization of a multimode stationary phase: Congo red derivatized silica in nano-flow HPLC

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