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Supra-assembly of siliceous vesicles

  • Hongning Wang
  • , Xufeng Zhou
  • , Meihua Yu
  • , Yunhua Wang
  • , Lu Han
  • , Jun Zhang
  • , Pei Yuan
  • , Graeme Auchterlonie
  • , Jin Zou
  • , Chengzhong Yu*
  • *此作品的通讯作者
  • Fudan University
  • University of Queensland

科研成果: 期刊稿件文章同行评审

摘要

We report a new approach to produce macroporous (∼110 nm in diameter) ordered siliceous foams (MOSF) by using block copolymers as templates in the absence of any organic cosolvent. The fine three-dimensional honeycomb structure of MOSF was determined by electron tomography. A formation mechanism of MOSF that spans from the atomic to macroscopic scale is proposed, which involves the cooperative self-assembly of unilamellar vesicles followed by the supra-assembly of vesicles. The fusion of soft vesicles finally leads to MOSF with well-ordered and defined honeycomb structures.

源语言英语
页(从-至)15992-15993
页数2
期刊Journal of the American Chemical Society
128
50
DOI
出版状态已出版 - 20 12月 2006
已对外发布

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