Sulfide synthesis through copper-catalyzed C-S bond formation under biomolecule-compatible conditions

Yonghong Zhang; Yiming Li; Xiaomei Zhang; Xuefeng Jiang

doi:10.1039/c4cc08367a

Sulfide synthesis through copper-catalyzed C-S bond formation under biomolecule-compatible conditions

Yonghong Zhang
, Yiming Li
, Xiaomei Zhang
, Xuefeng Jiang^*

^*此作品的通讯作者

化学与分子工程学院

East China Normal University
CAS - Chengdu Institute of Organic Chemistry
University of Chinese Academy of Sciences
CAS - Shanghai Institute of Organic Chemistry

科研成果: 期刊稿件 › 文章 › 同行评审

130 引用（Scopus）

摘要

We report here an efficient and mild method for constructing C-S bonds. The reactions were carried out with Na₂S₂O₃ as a sulfurating reagent, CuSO₄ as a catalyst, and water as solvent without any surfactant. The products were achieved in moderate to excellent yields at room temperature under air. Notably, this reaction is compatible with various biomolecules including amino acids, oligosaccharides, nucleosides, proteins, and cell lysates.

源语言	英语
页（从-至）	941-944
页数	4
期刊	Chemical Communications
卷	51
期	5
DOI	https://doi.org/10.1039/c4cc08367a
出版状态	已出版 - 18 1月 2015

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abstract = "We report here an efficient and mild method for constructing C-S bonds. The reactions were carried out with Na2S2O3 as a sulfurating reagent, CuSO4 as a catalyst, and water as solvent without any surfactant. The products were achieved in moderate to excellent yields at room temperature under air. Notably, this reaction is compatible with various biomolecules including amino acids, oligosaccharides, nucleosides, proteins, and cell lysates.",

author = "Yonghong Zhang and Yiming Li and Xiaomei Zhang and Xuefeng Jiang",

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AU - Zhang, Yonghong

AU - Li, Yiming

AU - Zhang, Xiaomei

AU - Jiang, Xuefeng

PY - 2015/1/18

Y1 - 2015/1/18

N2 - We report here an efficient and mild method for constructing C-S bonds. The reactions were carried out with Na2S2O3 as a sulfurating reagent, CuSO4 as a catalyst, and water as solvent without any surfactant. The products were achieved in moderate to excellent yields at room temperature under air. Notably, this reaction is compatible with various biomolecules including amino acids, oligosaccharides, nucleosides, proteins, and cell lysates.

AB - We report here an efficient and mild method for constructing C-S bonds. The reactions were carried out with Na2S2O3 as a sulfurating reagent, CuSO4 as a catalyst, and water as solvent without any surfactant. The products were achieved in moderate to excellent yields at room temperature under air. Notably, this reaction is compatible with various biomolecules including amino acids, oligosaccharides, nucleosides, proteins, and cell lysates.

UR - https://www.scopus.com/pages/publications/84919683764

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DO - 10.1039/c4cc08367a

M3 - 文章

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ER -

Sulfide synthesis through copper-catalyzed C-S bond formation under biomolecule-compatible conditions

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