Styryl conjugated coumarin caged alcohol: Efficient photorelease by either one-photon long wavelength or two-photon NIR excitation

Chunyan Bao; Guanshui Fan; Qiuning Lin; Bo Li; Shuiyu Cheng; Qi Huang; Linyong Zhu

doi:10.1021/ol203188h

Styryl conjugated coumarin caged alcohol: Efficient photorelease by either one-photon long wavelength or two-photon NIR excitation

Chunyan Bao
, Guanshui Fan
, Qiuning Lin
, Bo Li
, Shuiyu Cheng
, Qi Huang
, Linyong Zhu^*

^*此作品的通讯作者

物理与电子科学学院

East China University of Science and Technology

科研成果: 期刊稿件 › 文章 › 同行评审

65 引用（Scopus）

摘要

The synthesis and photorelease properties of a new phototrigger for alcohols are described. Compared to ester 4 caged by the reported [7-(diethylamino)coumarin-4-yl]methoxycarbonyl (DEACM) phototrigger, the caged ester 3 shows an efficient single-photon photolysis efficiency upon irradiation of long wavelength light (λ = 475 nm) and a stronger two-photon photolysis sensitivity with 800 nm laser light. Its promising properties and the efficient photorelease of adenosine make it very useful as a caging group for biological applications.

源语言	英语
页（从-至）	572-575
页数	4
期刊	Organic Letters
卷	14
期	2
DOI	https://doi.org/10.1021/ol203188h
出版状态	已出版 - 20 1月 2012

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title = "Styryl conjugated coumarin caged alcohol: Efficient photorelease by either one-photon long wavelength or two-photon NIR excitation",

abstract = "The synthesis and photorelease properties of a new phototrigger for alcohols are described. Compared to ester 4 caged by the reported [7-(diethylamino)coumarin-4-yl]methoxycarbonyl (DEACM) phototrigger, the caged ester 3 shows an efficient single-photon photolysis efficiency upon irradiation of long wavelength light (λ = 475 nm) and a stronger two-photon photolysis sensitivity with 800 nm laser light. Its promising properties and the efficient photorelease of adenosine make it very useful as a caging group for biological applications.",

author = "Chunyan Bao and Guanshui Fan and Qiuning Lin and Bo Li and Shuiyu Cheng and Qi Huang and Linyong Zhu",

year = "2012",

month = jan,

day = "20",

doi = "10.1021/ol203188h",

language = "英语",

volume = "14",

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journal = "Organic Letters",

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TY - JOUR

T1 - Styryl conjugated coumarin caged alcohol

T2 - Efficient photorelease by either one-photon long wavelength or two-photon NIR excitation

AU - Bao, Chunyan

AU - Fan, Guanshui

AU - Lin, Qiuning

AU - Li, Bo

AU - Cheng, Shuiyu

AU - Huang, Qi

AU - Zhu, Linyong

PY - 2012/1/20

Y1 - 2012/1/20

N2 - The synthesis and photorelease properties of a new phototrigger for alcohols are described. Compared to ester 4 caged by the reported [7-(diethylamino)coumarin-4-yl]methoxycarbonyl (DEACM) phototrigger, the caged ester 3 shows an efficient single-photon photolysis efficiency upon irradiation of long wavelength light (λ = 475 nm) and a stronger two-photon photolysis sensitivity with 800 nm laser light. Its promising properties and the efficient photorelease of adenosine make it very useful as a caging group for biological applications.

AB - The synthesis and photorelease properties of a new phototrigger for alcohols are described. Compared to ester 4 caged by the reported [7-(diethylamino)coumarin-4-yl]methoxycarbonyl (DEACM) phototrigger, the caged ester 3 shows an efficient single-photon photolysis efficiency upon irradiation of long wavelength light (λ = 475 nm) and a stronger two-photon photolysis sensitivity with 800 nm laser light. Its promising properties and the efficient photorelease of adenosine make it very useful as a caging group for biological applications.

UR - https://www.scopus.com/pages/publications/84862907746

U2 - 10.1021/ol203188h

DO - 10.1021/ol203188h

M3 - 文章

C2 - 22201546

AN - SCOPUS:84862907746

SN - 1523-7060

VL - 14

SP - 572

EP - 575

JO - Organic Letters

JF - Organic Letters

IS - 2

ER -

Styryl conjugated coumarin caged alcohol: Efficient photorelease by either one-photon long wavelength or two-photon NIR excitation

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