Structure elucidation of the highly active titanosilicate catalyst Ti-YNU-1

Juanfang Ruan; Peng Wu; Ben Slater; Osamu Terasaki

doi:10.1002/anie.200501939

Structure elucidation of the highly active titanosilicate catalyst Ti-YNU-1

Juanfang Ruan^*
, Peng Wu
, Ben Slater
, Osamu Terasaki

^*此作品的通讯作者

化学与分子工程学院

Stockholm University
University College London

科研成果: 期刊稿件 › 文章 › 同行评审

70 引用（Scopus）

摘要

Between the sheets: The structure of the titanosilicate Ti-YNU-1 reveals a much larger spacing along the c axis between the MWW sheets than its lamellar precursor and 3D Ti-MWW (see picture). Formation of twelve-membered rings would explain this cell expansion, which results in increased steric accessibility and may explain the higher catalytic activity of Ti-YNU-1 relative to other titanosilicates. (Chemical Equation Presented).

源语言	英语
页（从-至）	6719-6723
页数	5
期刊	Angewandte Chemie - International Edition
卷	44
期	41
DOI	https://doi.org/10.1002/anie.200501939
出版状态	已出版 - 21 10月 2005

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abstract = "Between the sheets: The structure of the titanosilicate Ti-YNU-1 reveals a much larger spacing along the c axis between the MWW sheets than its lamellar precursor and 3D Ti-MWW (see picture). Formation of twelve-membered rings would explain this cell expansion, which results in increased steric accessibility and may explain the higher catalytic activity of Ti-YNU-1 relative to other titanosilicates. (Chemical Equation Presented).",

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AU - Slater, Ben

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AB - Between the sheets: The structure of the titanosilicate Ti-YNU-1 reveals a much larger spacing along the c axis between the MWW sheets than its lamellar precursor and 3D Ti-MWW (see picture). Formation of twelve-membered rings would explain this cell expansion, which results in increased steric accessibility and may explain the higher catalytic activity of Ti-YNU-1 relative to other titanosilicates. (Chemical Equation Presented).

KW - Layered compounds

KW - Silicates

KW - Structure elucidation

KW - Titanates

KW - Zeolite analogues

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JF - Angewandte Chemie - International Edition

IS - 41

ER -

Structure elucidation of the highly active titanosilicate catalyst Ti-YNU-1

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