Structure and characterization of a mixed valent iron molybdophosphate: (NH3CH2CH2NH3)8(H 3O)1.3Fe0.3IIFe0.7 IIIMo12O32(HPO4)2 (H 2PO4)6(OH)6·8.7H2O

Hengzhen Shi; Yongkui Shan; Mingyuan He; Yuyan Liu; Jisen Jiang

doi:10.1016/S0022-2860(03)00403-4

Structure and characterization of a mixed valent iron molybdophosphate: (NH₃CH₂CH₂NH₃)₈(H ₃O)_1.3Fe_0.3^IIFe_0.7 ^IIIMo₁₂O₃₂(HPO₄)₂ (H ₂PO₄)₆(OH)₆·8.7H₂O

Hengzhen Shi
, Yongkui Shan^*
, Mingyuan He
, Yuyan Liu
, Jisen Jiang

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

17 引用（Scopus）

摘要

A new iron molybdophosphate, (NH₃CH₂CH ₂NH₃)₈(H₃O)_1.3Fe _0.3^IIFe_0.7^IIMo₁₂O ₃₂-(HPO₄)₂(H₂PO₄) ₆(OH)6·8.7H₂O (1) has been synthesized under hydrothermal conditions and structurally characterized by single crystal X-ray diffractions. It crystallizes in the monoclinic, space group P2(1)/n, a = 15.845(7) Å, b = 15.867(7) Å, c = 17.132(8) Å, β = 92.794(5)°, Z = 2. The crystal structure of 1 contains the isolated polyanion units [FeMo₁₂O₃₂(HPO₄) ₂(H₂PO₄)₆(OH)₆] around which the portonated ethylenediamine ions, lattice water and the protonated water molecules are positioned. By hydrogen bond interactions the polyanions are interconnected to form a novel three-dimensional iron molybdophosphate. The Mössbauer spectra quantitatively ascertain the assignment and distribution of iron oxidation states, and reveal the properties of the magnetic structure. Other characterization by IR and thermal analysis are also described.

源语言	英语
页（从-至）	17-23
页数	7
期刊	Journal of Molecular Structure
卷	658
期	1-2
DOI	https://doi.org/10.1016/S0022-2860(03)00403-4
出版状态	已出版 - 30 9月 2003

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@article{cea54da7eb754426a261bbd7b626f22c,

title = "Structure and characterization of a mixed valent iron molybdophosphate: (NH3CH2CH2NH3)8(H 3O)1.3Fe0.3IIFe0.7 IIIMo12O32(HPO4)2 (H 2PO4)6(OH)6·8.7H2O",

abstract = "A new iron molybdophosphate, (NH3CH2CH 2NH3)8(H3O)1.3Fe 0.3IIFe0.7IIMo12O 32-(HPO4)2(H2PO4) 6(OH)6·8.7H2O (1) has been synthesized under hydrothermal conditions and structurally characterized by single crystal X-ray diffractions. It crystallizes in the monoclinic, space group P2(1)/n, a = 15.845(7) {\AA}, b = 15.867(7) {\AA}, c = 17.132(8) {\AA}, β = 92.794(5)°, Z = 2. The crystal structure of 1 contains the isolated polyanion units [FeMo12O32(HPO4) 2(H2PO4)6(OH)6] around which the portonated ethylenediamine ions, lattice water and the protonated water molecules are positioned. By hydrogen bond interactions the polyanions are interconnected to form a novel three-dimensional iron molybdophosphate. The M{\"o}ssbauer spectra quantitatively ascertain the assignment and distribution of iron oxidation states, and reveal the properties of the magnetic structure. Other characterization by IR and thermal analysis are also described.",

keywords = "Characterization, Cluster, Molybdophosphate, M{\"o}ssbauer spectrum, Single crystal",

author = "Hengzhen Shi and Yongkui Shan and Mingyuan He and Yuyan Liu and Jisen Jiang",

year = "2003",

month = sep,

day = "30",

doi = "10.1016/S0022-2860(03)00403-4",

language = "英语",

volume = "658",

pages = "17--23",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

number = "1-2",

}

TY - JOUR

T1 - Structure and characterization of a mixed valent iron molybdophosphate

T2 - (NH3CH2CH2NH3)8(H 3O)1.3Fe0.3IIFe0.7 IIIMo12O32(HPO4)2 (H 2PO4)6(OH)6·8.7H2O

AU - Shi, Hengzhen

AU - Shan, Yongkui

AU - He, Mingyuan

AU - Liu, Yuyan

AU - Jiang, Jisen

PY - 2003/9/30

Y1 - 2003/9/30

N2 - A new iron molybdophosphate, (NH3CH2CH 2NH3)8(H3O)1.3Fe 0.3IIFe0.7IIMo12O 32-(HPO4)2(H2PO4) 6(OH)6·8.7H2O (1) has been synthesized under hydrothermal conditions and structurally characterized by single crystal X-ray diffractions. It crystallizes in the monoclinic, space group P2(1)/n, a = 15.845(7) Å, b = 15.867(7) Å, c = 17.132(8) Å, β = 92.794(5)°, Z = 2. The crystal structure of 1 contains the isolated polyanion units [FeMo12O32(HPO4) 2(H2PO4)6(OH)6] around which the portonated ethylenediamine ions, lattice water and the protonated water molecules are positioned. By hydrogen bond interactions the polyanions are interconnected to form a novel three-dimensional iron molybdophosphate. The Mössbauer spectra quantitatively ascertain the assignment and distribution of iron oxidation states, and reveal the properties of the magnetic structure. Other characterization by IR and thermal analysis are also described.

AB - A new iron molybdophosphate, (NH3CH2CH 2NH3)8(H3O)1.3Fe 0.3IIFe0.7IIMo12O 32-(HPO4)2(H2PO4) 6(OH)6·8.7H2O (1) has been synthesized under hydrothermal conditions and structurally characterized by single crystal X-ray diffractions. It crystallizes in the monoclinic, space group P2(1)/n, a = 15.845(7) Å, b = 15.867(7) Å, c = 17.132(8) Å, β = 92.794(5)°, Z = 2. The crystal structure of 1 contains the isolated polyanion units [FeMo12O32(HPO4) 2(H2PO4)6(OH)6] around which the portonated ethylenediamine ions, lattice water and the protonated water molecules are positioned. By hydrogen bond interactions the polyanions are interconnected to form a novel three-dimensional iron molybdophosphate. The Mössbauer spectra quantitatively ascertain the assignment and distribution of iron oxidation states, and reveal the properties of the magnetic structure. Other characterization by IR and thermal analysis are also described.

KW - Characterization

KW - Cluster

KW - Molybdophosphate

KW - Mössbauer spectrum

KW - Single crystal

UR - https://www.scopus.com/pages/publications/0041886607

U2 - 10.1016/S0022-2860(03)00403-4

DO - 10.1016/S0022-2860(03)00403-4

M3 - 文章

AN - SCOPUS:0041886607

SN - 0022-2860

VL - 658

SP - 17

EP - 23

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 1-2

ER -

Structure and characterization of a mixed valent iron molybdophosphate: (NH3CH2CH2NH3)8(H 3O)1.3Fe0.3IIFe0.7 IIIMo12O32(HPO4)2 (H 2PO4)6(OH)6·8.7H2O

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Structure and characterization of a mixed valent iron molybdophosphate: (NH₃CH₂CH₂NH₃)₈(H ₃O)_1.3Fe_0.3^IIFe_0.7 ^IIIMo₁₂O₃₂(HPO₄)₂ (H ₂PO₄)₆(OH)₆·8.7H₂O