Simple, efficient and recyclable palladium catalytic system for Heck reaction in functionalized ionic liquid network

Ye Liu; Min Li; Yong Lu; Guo Hua Gao; Qin Yang; Ming Yuan He

doi:10.1016/j.catcom.2006.05.002

Simple, efficient and recyclable palladium catalytic system for Heck reaction in functionalized ionic liquid network

Ye Liu
, Min Li
, Yong Lu^*
, Guo Hua Gao
, Qin Yang
, Ming Yuan He

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

45 引用（Scopus）

摘要

In functionalized ionic liquid network of [BMIM][TPPMS] and [BMIM][OAc], PdCl₂(CH₃CN)₂ efficiently catalyzed the Heck reaction of bromobenzene to ethyl cinnamate with yield of 60% and without the activity loss even after 11 recycling uses. The beneficial influences of this ionic liquid network on activity and stability were explained in terms of synergic ligand effects of [BMIM][TPPMS] and [BMIM][OAc], no accumulation of sodium or ammonium bromides by using [BMIM][OAc] as base, and the positive effect of [BMIM]Br by avoiding the formation of palladium black. The generality of this ionic liquid system to the different substrates also gave the pleasing results.

源语言	英语
页（从-至）	985-989
页数	5
期刊	Catalysis Communications
卷	7
期	12
DOI	https://doi.org/10.1016/j.catcom.2006.05.002
出版状态	已出版 - 12月 2006

访问文件

10.1016/j.catcom.2006.05.002

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{b28dcc69220b4fcd9d796e9360d5523e,

title = "Simple, efficient and recyclable palladium catalytic system for Heck reaction in functionalized ionic liquid network",

abstract = "In functionalized ionic liquid network of [BMIM][TPPMS] and [BMIM][OAc], PdCl2(CH3CN)2 efficiently catalyzed the Heck reaction of bromobenzene to ethyl cinnamate with yield of 60\% and without the activity loss even after 11 recycling uses. The beneficial influences of this ionic liquid network on activity and stability were explained in terms of synergic ligand effects of [BMIM][TPPMS] and [BMIM][OAc], no accumulation of sodium or ammonium bromides by using [BMIM][OAc] as base, and the positive effect of [BMIM]Br by avoiding the formation of palladium black. The generality of this ionic liquid system to the different substrates also gave the pleasing results.",

keywords = "Functionalized ionic liquids, Heck reaction, Palladium catalyst",

author = "Ye Liu and Min Li and Yong Lu and Gao, \{Guo Hua\} and Qin Yang and He, \{Ming Yuan\}",

year = "2006",

month = dec,

doi = "10.1016/j.catcom.2006.05.002",

language = "英语",

volume = "7",

pages = "985--989",

journal = "Catalysis Communications",

issn = "1566-7367",

publisher = "Elsevier B.V.",

number = "12",

}

TY - JOUR

T1 - Simple, efficient and recyclable palladium catalytic system for Heck reaction in functionalized ionic liquid network

AU - Liu, Ye

AU - Li, Min

AU - Lu, Yong

AU - Gao, Guo Hua

AU - Yang, Qin

AU - He, Ming Yuan

PY - 2006/12

Y1 - 2006/12

N2 - In functionalized ionic liquid network of [BMIM][TPPMS] and [BMIM][OAc], PdCl2(CH3CN)2 efficiently catalyzed the Heck reaction of bromobenzene to ethyl cinnamate with yield of 60% and without the activity loss even after 11 recycling uses. The beneficial influences of this ionic liquid network on activity and stability were explained in terms of synergic ligand effects of [BMIM][TPPMS] and [BMIM][OAc], no accumulation of sodium or ammonium bromides by using [BMIM][OAc] as base, and the positive effect of [BMIM]Br by avoiding the formation of palladium black. The generality of this ionic liquid system to the different substrates also gave the pleasing results.

AB - In functionalized ionic liquid network of [BMIM][TPPMS] and [BMIM][OAc], PdCl2(CH3CN)2 efficiently catalyzed the Heck reaction of bromobenzene to ethyl cinnamate with yield of 60% and without the activity loss even after 11 recycling uses. The beneficial influences of this ionic liquid network on activity and stability were explained in terms of synergic ligand effects of [BMIM][TPPMS] and [BMIM][OAc], no accumulation of sodium or ammonium bromides by using [BMIM][OAc] as base, and the positive effect of [BMIM]Br by avoiding the formation of palladium black. The generality of this ionic liquid system to the different substrates also gave the pleasing results.

KW - Functionalized ionic liquids

KW - Heck reaction

KW - Palladium catalyst

UR - https://www.scopus.com/pages/publications/33750089275

U2 - 10.1016/j.catcom.2006.05.002

DO - 10.1016/j.catcom.2006.05.002

M3 - 文章

AN - SCOPUS:33750089275

SN - 1566-7367

VL - 7

SP - 985

EP - 989

JO - Catalysis Communications

JF - Catalysis Communications

IS - 12

ER -

Simple, efficient and recyclable palladium catalytic system for Heck reaction in functionalized ionic liquid network

摘要

访问文件

其它文件与链接

指纹

引用此