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Selective recognition of acetate ion by perimidinium-based receptors

  • East China Normal University

科研成果: 期刊稿件文章同行评审

摘要

The first perimidinium-based receptors 1 and 2 have been designed and synthesized. The anion binding properties of the receptors were evaluated in DMSO by UV-vis, fluorescence spectroscopy, and 1H NMR methods. The results demonstrate that both receptors 1 and 2 exhibit good selectivity to acetate. The (C- H)+· · ·X- type ionic hydrogen bonding between the perimidinium moieties and acetate is the key interaction for the recognition.

源语言英语
页(从-至)6292-6296
页数5
期刊Tetrahedron Letters
53
46
DOI
出版状态已出版 - 14 11月 2012

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