Sarcoglaucins A-I, new antifouling cembrane-type diterpenes from the South China Sea soft coral: Sarcophyton glaucum

Jing Zhang; Xuli Tang; Xiao Han; Danqing Feng; Xiangchao Luo; Leen Van Ofwegen; Pinglin Li; Guoqiang Li

doi:10.1039/c9qo00386j

Sarcoglaucins A-I, new antifouling cembrane-type diterpenes from the South China Sea soft coral: Sarcophyton glaucum

Jing Zhang
, Xuli Tang
, Xiao Han
, Danqing Feng
, Xiangchao Luo
, Leen Van Ofwegen
, Pinglin Li^*
, Guoqiang Li

^*此作品的通讯作者

Ocean University of China
Qingdao National Laboratory for Marine Science and Technology
Xiamen University
Naturalis Biodiversity Center

科研成果: 期刊稿件 › 文章 › 同行评审

33 引用（Scopus）

摘要

Nine new cembrane diterpenes, named sarcoglaucins A-I (1-9) along with three known analogues, trochelioid (10), 7α-hydroxy-Δ⁸⁽¹⁹⁾-deepoxysarcophine (11), and (-)-sartrochine (12), were isolated from the soft coral Sarcophyton glaucum collected at Xisha Islands in the South China Sea. The structures of all the compounds were established by extensive spectroscopic analysis. The absolute configurations of sarcoglaucins A and B with an unusual [10.3.2.1] cage-type structure were determined using X-ray diffraction and quantum chemical calculation methods. Sarcoglaucin B (2), sarcoglaucin E (5) and compounds 10-12 showed strong antifouling activity against the barnacle Balanus amphitrite.

源语言	英语
页（从-至）	2004-2013
页数	10
期刊	Organic Chemistry Frontiers
卷	6
期	12
DOI	https://doi.org/10.1039/c9qo00386j
出版状态	已出版 - 21 6月 2019
已对外发布	是

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title = "Sarcoglaucins A-I, new antifouling cembrane-type diterpenes from the South China Sea soft coral: Sarcophyton glaucum",

abstract = "Nine new cembrane diterpenes, named sarcoglaucins A-I (1-9) along with three known analogues, trochelioid (10), 7α-hydroxy-Δ8(19)-deepoxysarcophine (11), and (-)-sartrochine (12), were isolated from the soft coral Sarcophyton glaucum collected at Xisha Islands in the South China Sea. The structures of all the compounds were established by extensive spectroscopic analysis. The absolute configurations of sarcoglaucins A and B with an unusual [10.3.2.1] cage-type structure were determined using X-ray diffraction and quantum chemical calculation methods. Sarcoglaucin B (2), sarcoglaucin E (5) and compounds 10-12 showed strong antifouling activity against the barnacle Balanus amphitrite.",

author = "Jing Zhang and Xuli Tang and Xiao Han and Danqing Feng and Xiangchao Luo and Ofwegen, \{Leen Van\} and Pinglin Li and Guoqiang Li",

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day = "21",

doi = "10.1039/c9qo00386j",

language = "英语",

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T2 - Sarcophyton glaucum

AU - Zhang, Jing

AU - Tang, Xuli

AU - Han, Xiao

AU - Feng, Danqing

AU - Luo, Xiangchao

AU - Ofwegen, Leen Van

AU - Li, Pinglin

AU - Li, Guoqiang

PY - 2019/6/21

Y1 - 2019/6/21

N2 - Nine new cembrane diterpenes, named sarcoglaucins A-I (1-9) along with three known analogues, trochelioid (10), 7α-hydroxy-Δ8(19)-deepoxysarcophine (11), and (-)-sartrochine (12), were isolated from the soft coral Sarcophyton glaucum collected at Xisha Islands in the South China Sea. The structures of all the compounds were established by extensive spectroscopic analysis. The absolute configurations of sarcoglaucins A and B with an unusual [10.3.2.1] cage-type structure were determined using X-ray diffraction and quantum chemical calculation methods. Sarcoglaucin B (2), sarcoglaucin E (5) and compounds 10-12 showed strong antifouling activity against the barnacle Balanus amphitrite.

AB - Nine new cembrane diterpenes, named sarcoglaucins A-I (1-9) along with three known analogues, trochelioid (10), 7α-hydroxy-Δ8(19)-deepoxysarcophine (11), and (-)-sartrochine (12), were isolated from the soft coral Sarcophyton glaucum collected at Xisha Islands in the South China Sea. The structures of all the compounds were established by extensive spectroscopic analysis. The absolute configurations of sarcoglaucins A and B with an unusual [10.3.2.1] cage-type structure were determined using X-ray diffraction and quantum chemical calculation methods. Sarcoglaucin B (2), sarcoglaucin E (5) and compounds 10-12 showed strong antifouling activity against the barnacle Balanus amphitrite.

UR - https://www.scopus.com/pages/publications/85067108005

U2 - 10.1039/c9qo00386j

DO - 10.1039/c9qo00386j

M3 - 文章

AN - SCOPUS:85067108005

SN - 2052-4110

VL - 6

SP - 2004

EP - 2013

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 12

ER -

Sarcoglaucins A-I, new antifouling cembrane-type diterpenes from the South China Sea soft coral: Sarcophyton glaucum

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