Ring-Opening Intramolecular Arylation of 1,2-Disubtituted Epoxides with Tuneable Stereoselectivity

Cong Cong Zhao; Chaoren Shen; Bin Wang; Liangce Rong; Kaiwu Dong

doi:10.1002/ejoc.202301271

Ring-Opening Intramolecular Arylation of 1,2-Disubtituted Epoxides with Tuneable Stereoselectivity

Cong Cong Zhao
, Chaoren Shen
, Bin Wang
, Liangce Rong^*
, Kaiwu Dong^*

^*此作品的通讯作者

化学与分子工程学院

Jiangsu Normal University
East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

1 引用（Scopus）

摘要

A method of stereodivergent intramolecular ring-opening arylation of amine-tethered epoxides to 3,4-disubstituted tetrahydroquinolines has been developed. The tuneable good stereoselectivity was attained by changing the catalyst from titanocene(III) catalyst to Lewis-acidic zinc catalyst.

源语言	英语
文章编号	e202301271
期刊	European Journal of Organic Chemistry
卷	27
期	9
DOI	https://doi.org/10.1002/ejoc.202301271
出版状态	已出版 - 1 3月 2024

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title = "Ring-Opening Intramolecular Arylation of 1,2-Disubtituted Epoxides with Tuneable Stereoselectivity",

abstract = "A method of stereodivergent intramolecular ring-opening arylation of amine-tethered epoxides to 3,4-disubstituted tetrahydroquinolines has been developed. The tuneable good stereoselectivity was attained by changing the catalyst from titanocene(III) catalyst to Lewis-acidic zinc catalyst.",

keywords = "Lewis acid, arylation, epoxide, stereoselectivity, titanocene",

author = "Zhao, \{Cong Cong\} and Chaoren Shen and Bin Wang and Liangce Rong and Kaiwu Dong",

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doi = "10.1002/ejoc.202301271",

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AU - Zhao, Cong Cong

AU - Shen, Chaoren

AU - Wang, Bin

AU - Rong, Liangce

AU - Dong, Kaiwu

PY - 2024/3/1

Y1 - 2024/3/1

N2 - A method of stereodivergent intramolecular ring-opening arylation of amine-tethered epoxides to 3,4-disubstituted tetrahydroquinolines has been developed. The tuneable good stereoselectivity was attained by changing the catalyst from titanocene(III) catalyst to Lewis-acidic zinc catalyst.

AB - A method of stereodivergent intramolecular ring-opening arylation of amine-tethered epoxides to 3,4-disubstituted tetrahydroquinolines has been developed. The tuneable good stereoselectivity was attained by changing the catalyst from titanocene(III) catalyst to Lewis-acidic zinc catalyst.

KW - Lewis acid

KW - arylation

KW - epoxide

KW - stereoselectivity

KW - titanocene

UR - https://www.scopus.com/pages/publications/85185479682

U2 - 10.1002/ejoc.202301271

DO - 10.1002/ejoc.202301271

M3 - 文章

AN - SCOPUS:85185479682

SN - 1434-193X

VL - 27

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

IS - 9

M1 - e202301271

ER -

Ring-Opening Intramolecular Arylation of 1,2-Disubtituted Epoxides with Tuneable Stereoselectivity

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