TY - JOUR
T1 - Polyfluoroalkoxylation and methoxylation of polychloropyridines
AU - Xu, Xiaoyong
AU - Qian, Xuhong
AU - Li, Zhong
AU - Song, Gonghua
PY - 1998/2/27
Y1 - 1998/2/27
N2 - With sodium 2,2,2-trifluoroethoxide, sodium 1,1,1,3,3,3-hexafluoro-2-propoxide and sodium methoxide used as nucleophilic reagents, the alcoholysis reactions of 2,3,4,5,6-pentachloropyridine and 2,3,5,6-tetrachloropyridine were studied. Some new polyfluoroalkoxypyridines have been synthesized. The activities, pathways, mechanism of the alcoholysis reactions are discussed.
AB - With sodium 2,2,2-trifluoroethoxide, sodium 1,1,1,3,3,3-hexafluoro-2-propoxide and sodium methoxide used as nucleophilic reagents, the alcoholysis reactions of 2,3,4,5,6-pentachloropyridine and 2,3,5,6-tetrachloropyridine were studied. Some new polyfluoroalkoxypyridines have been synthesized. The activities, pathways, mechanism of the alcoholysis reactions are discussed.
KW - Alcoholysis
KW - Nucleophilic reagents
KW - Polychloropyridine
UR - https://www.scopus.com/pages/publications/0032570403
U2 - 10.1016/S0022-1139(97)00094-8
DO - 10.1016/S0022-1139(97)00094-8
M3 - 文章
AN - SCOPUS:0032570403
SN - 0022-1139
VL - 88
SP - 9
EP - 13
JO - Journal of Fluorine Chemistry
JF - Journal of Fluorine Chemistry
IS - 1
ER -