Poly[[diaqua(μ2-5,5-dioxodibenzo[b,d]thiophene-3, 7-dicarboxylato)(μ2-ethylene glycol)manganese(II)] dimethyl-acetamide solvate]

Xiu Chun Yi; Li Yan; En Qing Gao

doi:10.1107/S1600536810045411

Poly[[diaqua(μ₂-5,5-dioxodibenzo[b,d]thiophene-3, 7-dicarboxylato)(μ₂-ethylene glycol)manganese(II)] dimethyl-acetamide solvate]

Xiu Chun Yi
, Li Yan
, En Qing Gao^*

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

3 引用（Scopus）

摘要

In the title complex, {[Mn(C₁₄H₆O₆S) (C₂H₆O₂)(H₂O)₂] ·C₄H₉NO}_n , the Mn^II ion is six-coordinated in a trans-octa-hedral geometry by two carboxyl-ate O atoms from two 5,5-dioxodibenzo[b,d]thiophene-3,7-dicarboxyl-ate (L) ligands in a monodentate mode, two O atoms from two ethylene glycol (EG) molecules and two aqua O atoms. The metal ions are linked by the EG and L ligands, forming two-dimensional coordination networks, which are associated into the three-dimensional structure through O - H⋯O hydrogen bonds.

源语言	英语
页（从-至）	m1554
期刊	Acta Crystallographica Section E: Structure Reports Online
卷	66
期	12
DOI	https://doi.org/10.1107/S1600536810045411
出版状态	已出版 - 12月 2010

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10.1107/S1600536810045411

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引用此

@article{e1e81b482e6f4641a3907509db4f4ba0,

title = "Poly[[diaqua(μ2-5,5-dioxodibenzo[b,d]thiophene-3, 7-dicarboxylato)(μ2-ethylene glycol)manganese(II)] dimethyl-acetamide solvate]",

abstract = "In the title complex, \{[Mn(C14H6O6S) (C2H6O2)(H2O)2] ·C4H9NO\}n , the MnII ion is six-coordinated in a trans-octa-hedral geometry by two carboxyl-ate O atoms from two 5,5-dioxodibenzo[b,d]thiophene-3,7-dicarboxyl-ate (L) ligands in a monodentate mode, two O atoms from two ethylene glycol (EG) molecules and two aqua O atoms. The metal ions are linked by the EG and L ligands, forming two-dimensional coordination networks, which are associated into the three-dimensional structure through O - H⋯O hydrogen bonds.",

author = "Yi, \{Xiu Chun\} and Li Yan and Gao, \{En Qing\}",

year = "2010",

month = dec,

doi = "10.1107/S1600536810045411",

language = "英语",

volume = "66",

pages = "m1554",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "12",

}

TY - JOUR

T1 - Poly[[diaqua(μ2-5,5-dioxodibenzo[b,d]thiophene-3, 7-dicarboxylato)(μ2-ethylene glycol)manganese(II)] dimethyl-acetamide solvate]

AU - Yi, Xiu Chun

AU - Yan, Li

AU - Gao, En Qing

PY - 2010/12

Y1 - 2010/12

N2 - In the title complex, {[Mn(C14H6O6S) (C2H6O2)(H2O)2] ·C4H9NO}n , the MnII ion is six-coordinated in a trans-octa-hedral geometry by two carboxyl-ate O atoms from two 5,5-dioxodibenzo[b,d]thiophene-3,7-dicarboxyl-ate (L) ligands in a monodentate mode, two O atoms from two ethylene glycol (EG) molecules and two aqua O atoms. The metal ions are linked by the EG and L ligands, forming two-dimensional coordination networks, which are associated into the three-dimensional structure through O - H⋯O hydrogen bonds.

AB - In the title complex, {[Mn(C14H6O6S) (C2H6O2)(H2O)2] ·C4H9NO}n , the MnII ion is six-coordinated in a trans-octa-hedral geometry by two carboxyl-ate O atoms from two 5,5-dioxodibenzo[b,d]thiophene-3,7-dicarboxyl-ate (L) ligands in a monodentate mode, two O atoms from two ethylene glycol (EG) molecules and two aqua O atoms. The metal ions are linked by the EG and L ligands, forming two-dimensional coordination networks, which are associated into the three-dimensional structure through O - H⋯O hydrogen bonds.

UR - https://www.scopus.com/pages/publications/78650096261

U2 - 10.1107/S1600536810045411

DO - 10.1107/S1600536810045411

M3 - 文章

AN - SCOPUS:78650096261

SN - 1600-5368

VL - 66

SP - m1554

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

Poly[[diaqua(μ2-5,5-dioxodibenzo[b,d]thiophene-3, 7-dicarboxylato)(μ2-ethylene glycol)manganese(II)] dimethyl-acetamide solvate]

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Poly[[diaqua(μ₂-5,5-dioxodibenzo[b,d]thiophene-3, 7-dicarboxylato)(μ₂-ethylene glycol)manganese(II)] dimethyl-acetamide solvate]