Photoelectron Imaging Spectroscopy of ZrO- Diatomic Anion

Qing Yu Liu; Lian Rui Hu; Hui Chen; Sheng Gui He

doi:10.1063/1674-0068/28/cjcp1505090

Photoelectron Imaging Spectroscopy of ZrO^- Diatomic Anion

Qing Yu Liu
, Lian Rui Hu
, Hui Chen^*
, Sheng Gui He

^*此作品的通讯作者

Chinese Academy of Sciences
CAS - Institute of Chemistry

科研成果: 期刊稿件 › 文章 › 同行评审

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摘要

The diatomic ZrO^- anion has been prepared by laser ablation and studied by photoelectron imaging spectroscopy combined with quantum chemistry calculations. The observed photoelectron spectra can be well assigned on the basis of reported optical spectroscopy and high-level ab initio calculations. The ground state of ZrO^- is a ²Δ state with spin-orbit splitting of 578±12 cm^-1. The electron affinity of ZrO is 1.249±0.005 eV. For the first time, the c³σ^- state of ZrO has been experimentally observed at 13316±24 cm^-1 with respect to the X¹σ⁺ ground state. A comparison between ZrO and the isoelectronic molecule NbN has been made.

源语言	英语
页（从-至）	452-458
页数	7
期刊	Chinese Journal of Chemical Physics
卷	28
期	4
DOI	https://doi.org/10.1063/1674-0068/28/cjcp1505090
出版状态	已出版 - 27 8月 2015
已对外发布	是

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@article{d9308494c83448949d0c263f4934a179,

title = "Photoelectron Imaging Spectroscopy of ZrO- Diatomic Anion",

abstract = "The diatomic ZrO- anion has been prepared by laser ablation and studied by photoelectron imaging spectroscopy combined with quantum chemistry calculations. The observed photoelectron spectra can be well assigned on the basis of reported optical spectroscopy and high-level ab initio calculations. The ground state of ZrO- is a 2Δ state with spin-orbit splitting of 578±12 cm-1. The electron affinity of ZrO is 1.249±0.005 eV. For the first time, the c3σ- state of ZrO has been experimentally observed at 13316±24 cm-1 with respect to the X1σ+ ground state. A comparison between ZrO and the isoelectronic molecule NbN has been made.",

author = "Liu, \{Qing Yu\} and Hu, \{Lian Rui\} and Hui Chen and He, \{Sheng Gui\}",

note = "Publisher Copyright: {\textcopyright} 2015 Chinese Physical Society.",

year = "2015",

month = aug,

day = "27",

doi = "10.1063/1674-0068/28/cjcp1505090",

language = "英语",

volume = "28",

pages = "452--458",

journal = "Chinese Journal of Chemical Physics",

issn = "1674-0068",

publisher = "American Institute of Physics",

number = "4",

}

TY - JOUR

T1 - Photoelectron Imaging Spectroscopy of ZrO- Diatomic Anion

AU - Liu, Qing Yu

AU - Hu, Lian Rui

AU - Chen, Hui

AU - He, Sheng Gui

PY - 2015/8/27

Y1 - 2015/8/27

N2 - The diatomic ZrO- anion has been prepared by laser ablation and studied by photoelectron imaging spectroscopy combined with quantum chemistry calculations. The observed photoelectron spectra can be well assigned on the basis of reported optical spectroscopy and high-level ab initio calculations. The ground state of ZrO- is a 2Δ state with spin-orbit splitting of 578±12 cm-1. The electron affinity of ZrO is 1.249±0.005 eV. For the first time, the c3σ- state of ZrO has been experimentally observed at 13316±24 cm-1 with respect to the X1σ+ ground state. A comparison between ZrO and the isoelectronic molecule NbN has been made.

AB - The diatomic ZrO- anion has been prepared by laser ablation and studied by photoelectron imaging spectroscopy combined with quantum chemistry calculations. The observed photoelectron spectra can be well assigned on the basis of reported optical spectroscopy and high-level ab initio calculations. The ground state of ZrO- is a 2Δ state with spin-orbit splitting of 578±12 cm-1. The electron affinity of ZrO is 1.249±0.005 eV. For the first time, the c3σ- state of ZrO has been experimentally observed at 13316±24 cm-1 with respect to the X1σ+ ground state. A comparison between ZrO and the isoelectronic molecule NbN has been made.

UR - https://www.scopus.com/pages/publications/84941960486

U2 - 10.1063/1674-0068/28/cjcp1505090

DO - 10.1063/1674-0068/28/cjcp1505090

M3 - 文章

AN - SCOPUS:84941960486

SN - 1674-0068

VL - 28

SP - 452

EP - 458

JO - Chinese Journal of Chemical Physics

JF - Chinese Journal of Chemical Physics

IS - 4

ER -

Photoelectron Imaging Spectroscopy of ZrO- Diatomic Anion

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Photoelectron Imaging Spectroscopy of ZrO^- Diatomic Anion