Performance enhancement of polymer solar cells with luminescent down-shifting sensitizer

Enhanced performance of polymer solar cells is reported by incorporating a solution-processed luminescent down-shifting (LDS) sensitizer, which is composed of a C545T fluorescent molecule doped tris(8-quinolinolato) aluminum (C545T:Alq₃). An optimized LDS sensitizer can result in ∼15% enhancement in power conversion efficiency than the reference device with pristine Alq₃. The performance enhancement is associated with the increase in photocurrent induced by LDS sensitizer, which is capable of absorbing short-wavelength solar spectrum and re-emitting long-wavelength light, which is complementary with the absorption spectrum of the active layer. This method provides a facile approach for high-performance polymer solar cell designs.