Palladium-catalyzed synthesis of fluoreones from bis(2-bromophenyl)methanols

Qian Gao; Senmiao Xu

doi:10.1039/c7ob02895d

Palladium-catalyzed synthesis of fluoreones from bis(2-bromophenyl)methanols

Qian Gao
, Senmiao Xu^*

^*此作品的通讯作者

CAS - Lanzhou Institute of Chemical Physics

科研成果: 期刊稿件 › 文章 › 同行评审

11 引用（Scopus）

摘要

A palladium-catalyzed synthesis method of fluorenones has been developed. A variety of bis(2-bromophenyl)methanols could undergo the reaction smoothly in the presence of Pd(OAc)₂, affording a series of fluorenones in moderate to good yields (two steps). Mechanistic studies reveal that the reaction might be triggered by oxidation of alcohol followed by intramolecular reductive coupling.

源语言	英语
页（从-至）	208-212
页数	5
期刊	Organic and Biomolecular Chemistry
卷	16
期	2
DOI	https://doi.org/10.1039/c7ob02895d
出版状态	已出版 - 2018
已对外发布	是

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10.1039/c7ob02895d

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title = "Palladium-catalyzed synthesis of fluoreones from bis(2-bromophenyl)methanols",

abstract = "A palladium-catalyzed synthesis method of fluorenones has been developed. A variety of bis(2-bromophenyl)methanols could undergo the reaction smoothly in the presence of Pd(OAc)2, affording a series of fluorenones in moderate to good yields (two steps). Mechanistic studies reveal that the reaction might be triggered by oxidation of alcohol followed by intramolecular reductive coupling.",

author = "Qian Gao and Senmiao Xu",

note = "Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

year = "2018",

doi = "10.1039/c7ob02895d",

language = "英语",

volume = "16",

pages = "208--212",

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T1 - Palladium-catalyzed synthesis of fluoreones from bis(2-bromophenyl)methanols

AU - Gao, Qian

AU - Xu, Senmiao

PY - 2018

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N2 - A palladium-catalyzed synthesis method of fluorenones has been developed. A variety of bis(2-bromophenyl)methanols could undergo the reaction smoothly in the presence of Pd(OAc)2, affording a series of fluorenones in moderate to good yields (two steps). Mechanistic studies reveal that the reaction might be triggered by oxidation of alcohol followed by intramolecular reductive coupling.

AB - A palladium-catalyzed synthesis method of fluorenones has been developed. A variety of bis(2-bromophenyl)methanols could undergo the reaction smoothly in the presence of Pd(OAc)2, affording a series of fluorenones in moderate to good yields (two steps). Mechanistic studies reveal that the reaction might be triggered by oxidation of alcohol followed by intramolecular reductive coupling.

UR - https://www.scopus.com/pages/publications/85040165901

U2 - 10.1039/c7ob02895d

DO - 10.1039/c7ob02895d

M3 - 文章

C2 - 29256561

AN - SCOPUS:85040165901

SN - 1477-0520

VL - 16

SP - 208

EP - 212

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 2

ER -

Palladium-catalyzed synthesis of fluoreones from bis(2-bromophenyl)methanols

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