Palladium-catalyzed heck reaction in the multi-functionalized ionic liquid compositions

Qing Xia Wan; Ye Liu; Yong Lu; Min Li; Hai Hong Wu

doi:10.1007/s10562-007-9343-y

Palladium-catalyzed heck reaction in the multi-functionalized ionic liquid compositions

Qing Xia Wan
, Ye Liu^*
, Yong Lu
, Min Li
, Hai Hong Wu

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

39 引用（Scopus）

摘要

In the multi-functionalized ionic liquid compositions (MFILC), composed of 1-n-butyl-2-diphenylphosphino-3-methylimidazolium hexafluorophosphate, [BDPPMIM]PF6), 1-(2-piperid-1-yl-ethyl)-3-methylimidazolium hexafluorophosphate, [PEMIM]PF6), and 1-n-butyl-3-methylimidazolium hexafluorophosphate ([BMIM]PF6), PdCl2 served as an efficient catalyst for Heck reactions of aryl iodides and bromides. The built-up PdCl2-MFILC, including stoichiometrically consumed base of [PEMIM]PF6, could be reused at least for seven cycles without activity loss.

源语言	英语
页（从-至）	331-336
页数	6
期刊	Catalysis Letters
卷	121
期	3-4
DOI	https://doi.org/10.1007/s10562-007-9343-y
出版状态	已出版 - 3月 2008

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@article{b0c2749e0dc34c35aa3e7821acda85e6,

title = "Palladium-catalyzed heck reaction in the multi-functionalized ionic liquid compositions",

abstract = "In the multi-functionalized ionic liquid compositions (MFILC), composed of 1-n-butyl-2-diphenylphosphino-3-methylimidazolium hexafluorophosphate, [BDPPMIM]PF6), 1-(2-piperid-1-yl-ethyl)-3-methylimidazolium hexafluorophosphate, [PEMIM]PF6), and 1-n-butyl-3-methylimidazolium hexafluorophosphate ([BMIM]PF6), PdCl2 served as an efficient catalyst for Heck reactions of aryl iodides and bromides. The built-up PdCl2-MFILC, including stoichiometrically consumed base of [PEMIM]PF6, could be reused at least for seven cycles without activity loss.",

keywords = "Functionalization, Heck reaction, Ionic liquids, Palladium catalyst",

author = "Wan, \{Qing Xia\} and Ye Liu and Yong Lu and Min Li and Wu, \{Hai Hong\}",

year = "2008",

month = mar,

doi = "10.1007/s10562-007-9343-y",

language = "英语",

volume = "121",

pages = "331--336",

journal = "Catalysis Letters",

issn = "1011-372X",

publisher = "Kluwer Academic Publishers",

number = "3-4",

}

TY - JOUR

T1 - Palladium-catalyzed heck reaction in the multi-functionalized ionic liquid compositions

AU - Wan, Qing Xia

AU - Liu, Ye

AU - Lu, Yong

AU - Li, Min

AU - Wu, Hai Hong

PY - 2008/3

Y1 - 2008/3

N2 - In the multi-functionalized ionic liquid compositions (MFILC), composed of 1-n-butyl-2-diphenylphosphino-3-methylimidazolium hexafluorophosphate, [BDPPMIM]PF6), 1-(2-piperid-1-yl-ethyl)-3-methylimidazolium hexafluorophosphate, [PEMIM]PF6), and 1-n-butyl-3-methylimidazolium hexafluorophosphate ([BMIM]PF6), PdCl2 served as an efficient catalyst for Heck reactions of aryl iodides and bromides. The built-up PdCl2-MFILC, including stoichiometrically consumed base of [PEMIM]PF6, could be reused at least for seven cycles without activity loss.

AB - In the multi-functionalized ionic liquid compositions (MFILC), composed of 1-n-butyl-2-diphenylphosphino-3-methylimidazolium hexafluorophosphate, [BDPPMIM]PF6), 1-(2-piperid-1-yl-ethyl)-3-methylimidazolium hexafluorophosphate, [PEMIM]PF6), and 1-n-butyl-3-methylimidazolium hexafluorophosphate ([BMIM]PF6), PdCl2 served as an efficient catalyst for Heck reactions of aryl iodides and bromides. The built-up PdCl2-MFILC, including stoichiometrically consumed base of [PEMIM]PF6, could be reused at least for seven cycles without activity loss.

KW - Functionalization

KW - Heck reaction

KW - Ionic liquids

KW - Palladium catalyst

UR - https://www.scopus.com/pages/publications/39149129072

U2 - 10.1007/s10562-007-9343-y

DO - 10.1007/s10562-007-9343-y

M3 - 文章

AN - SCOPUS:39149129072

SN - 1011-372X

VL - 121

SP - 331

EP - 336

JO - Catalysis Letters

JF - Catalysis Letters

IS - 3-4

ER -

Palladium-catalyzed heck reaction in the multi-functionalized ionic liquid compositions

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