Oxalic acid as the: In situ carbon monoxide generator in palladium-catalyzed hydroxycarbonylation of arylhalides

Changdong Shao; Ailan Lu; Xiaoling Wang; Bo Zhou; Xiaohong Guan; Yanghui Zhang

doi:10.1039/c7ob01052d

Oxalic acid as the: In situ carbon monoxide generator in palladium-catalyzed hydroxycarbonylation of arylhalides

Changdong Shao
, Ailan Lu
, Xiaoling Wang
, Bo Zhou
, Xiaohong Guan
, Yanghui Zhang

Tongji University
Shanghai Key Laboratory of Chemical Assessment and Sustainability

科研成果: 期刊稿件 › 文章 › 同行评审

41 引用（Scopus）

摘要

An efficient palladium-catalyzed hydroxycarbonylation reaction of arylhalides using oxalic acid as a CO source has been developed. The reaction features high safety, low catalyst loading, and a broad substrate scope, and provides a safe and tractable approach to access a variety of aromatic carboxylic acid compounds. Mechanistic studies revealed the decomposition pattern of oxalic acid.

源语言	英语
页（从-至）	5033-5040
页数	8
期刊	Organic and Biomolecular Chemistry
卷	15
期	23
DOI	https://doi.org/10.1039/c7ob01052d
出版状态	已出版 - 2017
已对外发布	是

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abstract = "An efficient palladium-catalyzed hydroxycarbonylation reaction of arylhalides using oxalic acid as a CO source has been developed. The reaction features high safety, low catalyst loading, and a broad substrate scope, and provides a safe and tractable approach to access a variety of aromatic carboxylic acid compounds. Mechanistic studies revealed the decomposition pattern of oxalic acid.",

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AU - Zhou, Bo

AU - Guan, Xiaohong

AU - Zhang, Yanghui

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AB - An efficient palladium-catalyzed hydroxycarbonylation reaction of arylhalides using oxalic acid as a CO source has been developed. The reaction features high safety, low catalyst loading, and a broad substrate scope, and provides a safe and tractable approach to access a variety of aromatic carboxylic acid compounds. Mechanistic studies revealed the decomposition pattern of oxalic acid.

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Oxalic acid as the: In situ carbon monoxide generator in palladium-catalyzed hydroxycarbonylation of arylhalides

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