Nucleophilic substitution of hydrogen in naphthalene by chloride (Cl -) in ionic liquids

Shen Yi Shi; Ai Guo Kong; Xin Hua Zhao; Han Ming Ding; Fan Yang; Yong Kui Shan

doi:10.1016/j.cclet.2010.09.021

Nucleophilic substitution of hydrogen in naphthalene by chloride (Cl ^-) in ionic liquids

Shen Yi Shi
, Ai Guo Kong
, Xin Hua Zhao
, Han Ming Ding
, Fan Yang
, Yong Kui Shan

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

5 引用（Scopus）

摘要

Nucleophilic aromatic substitution of hydrogen in non-activated aromatic ring, a very rare phenomenon in organic chemistry, is found in ionic liquids containing Cl^- as anion under mild reaction conditions. The reaction may be carried out by the addition of the halogen-bonding adduct (Br ₂Cl^-) as nucleophile to aromatic ring carbon atom, leading to the formation of the nucleophilic substitution product.

源语言	英语
页（从-至）	147-150
页数	4
期刊	Chinese Chemical Letters
卷	22
期	2
DOI	https://doi.org/10.1016/j.cclet.2010.09.021
出版状态	已出版 - 2月 2011

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10.1016/j.cclet.2010.09.021

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title = "Nucleophilic substitution of hydrogen in naphthalene by chloride (Cl -) in ionic liquids",

abstract = "Nucleophilic aromatic substitution of hydrogen in non-activated aromatic ring, a very rare phenomenon in organic chemistry, is found in ionic liquids containing Cl- as anion under mild reaction conditions. The reaction may be carried out by the addition of the halogen-bonding adduct (Br 2Cl-) as nucleophile to aromatic ring carbon atom, leading to the formation of the nucleophilic substitution product.",

keywords = "Aromatic compound, Halogen bonding, Ionic liquid, Naphthalene, Nucleophilic reaction",

author = "Shi, \{Shen Yi\} and Kong, \{Ai Guo\} and Zhao, \{Xin Hua\} and Ding, \{Han Ming\} and Fan Yang and Shan, \{Yong Kui\}",

year = "2011",

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doi = "10.1016/j.cclet.2010.09.021",

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volume = "22",

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T1 - Nucleophilic substitution of hydrogen in naphthalene by chloride (Cl -) in ionic liquids

AU - Shi, Shen Yi

AU - Kong, Ai Guo

AU - Zhao, Xin Hua

AU - Ding, Han Ming

AU - Yang, Fan

AU - Shan, Yong Kui

PY - 2011/2

Y1 - 2011/2

N2 - Nucleophilic aromatic substitution of hydrogen in non-activated aromatic ring, a very rare phenomenon in organic chemistry, is found in ionic liquids containing Cl- as anion under mild reaction conditions. The reaction may be carried out by the addition of the halogen-bonding adduct (Br 2Cl-) as nucleophile to aromatic ring carbon atom, leading to the formation of the nucleophilic substitution product.

AB - Nucleophilic aromatic substitution of hydrogen in non-activated aromatic ring, a very rare phenomenon in organic chemistry, is found in ionic liquids containing Cl- as anion under mild reaction conditions. The reaction may be carried out by the addition of the halogen-bonding adduct (Br 2Cl-) as nucleophile to aromatic ring carbon atom, leading to the formation of the nucleophilic substitution product.

KW - Aromatic compound

KW - Halogen bonding

KW - Ionic liquid

KW - Naphthalene

KW - Nucleophilic reaction

UR - https://www.scopus.com/pages/publications/78651292648

U2 - 10.1016/j.cclet.2010.09.021

DO - 10.1016/j.cclet.2010.09.021

M3 - 文章

AN - SCOPUS:78651292648

SN - 1001-8417

VL - 22

SP - 147

EP - 150

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 2

ER -

Nucleophilic substitution of hydrogen in naphthalene by chloride (Cl -) in ionic liquids

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Nucleophilic substitution of hydrogen in naphthalene by chloride (Cl ^-) in ionic liquids