Nonionic block copolymer synthesis of large-pore cubic mesoporous single crystals by use of inorganic salts

Chengzhong Yu; Bozhi Tian; Jie Fan; Galen D. Stucky; Dongyuan Zhao

doi:10.1021/ja025548f

Nonionic block copolymer synthesis of large-pore cubic mesoporous single crystals by use of inorganic salts

Chengzhong Yu
, Bozhi Tian
, Jie Fan
, Galen D. Stucky
, Dongyuan Zhao^*

^*此作品的通讯作者

Fudan University
University of California at Santa Barbara

科研成果: 期刊稿件 › 文章 › 同行评审

325 引用（Scopus）

摘要

Large-pore cubic (Im3m) mesoporous silica single crystals have been synthesized by using commercial nonionic block copolymers as templates and inorganic salts as additives. These single crystals possess exclusively uniform rhombdodecahedron shapes (∼1 μm) with ∼100% yield. The mesopore lattice array in each crystal face is solved by TEM, further confirming that these crystals are perfect single crystals.

源语言	英语
页（从-至）	4556-4557
页数	2
期刊	Journal of the American Chemical Society
卷	124
期	17
DOI	https://doi.org/10.1021/ja025548f
出版状态	已出版 - 1 5月 2002
已对外发布	是

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10.1021/ja025548f

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abstract = "Large-pore cubic (Im3m) mesoporous silica single crystals have been synthesized by using commercial nonionic block copolymers as templates and inorganic salts as additives. These single crystals possess exclusively uniform rhombdodecahedron shapes (∼1 μm) with ∼100\% yield. The mesopore lattice array in each crystal face is solved by TEM, further confirming that these crystals are perfect single crystals.",

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AU - Tian, Bozhi

AU - Fan, Jie

AU - Stucky, Galen D.

AU - Zhao, Dongyuan

PY - 2002/5/1

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N2 - Large-pore cubic (Im3m) mesoporous silica single crystals have been synthesized by using commercial nonionic block copolymers as templates and inorganic salts as additives. These single crystals possess exclusively uniform rhombdodecahedron shapes (∼1 μm) with ∼100% yield. The mesopore lattice array in each crystal face is solved by TEM, further confirming that these crystals are perfect single crystals.

AB - Large-pore cubic (Im3m) mesoporous silica single crystals have been synthesized by using commercial nonionic block copolymers as templates and inorganic salts as additives. These single crystals possess exclusively uniform rhombdodecahedron shapes (∼1 μm) with ∼100% yield. The mesopore lattice array in each crystal face is solved by TEM, further confirming that these crystals are perfect single crystals.

UR - https://www.scopus.com/pages/publications/0036569852

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DO - 10.1021/ja025548f

M3 - 文章

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Nonionic block copolymer synthesis of large-pore cubic mesoporous single crystals by use of inorganic salts

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