Nanoengineering Metal–Organic Framework-Based Materials for Use in Electrochemical CO₂ Reduction Reactions

Electrocatalytic reduction of carbon dioxide to valuable chemicals is a sustainable technology that can achieve a carbon-neutral energy cycle in the environment. Electrochemical CO₂ reduction reaction (CO₂RR) processes using metal–organic frameworks (MOFs), featuring atomically dispersed active sites, large surface area, high porosity, controllable morphology, and remarkable tunability, have attracted considerable research attention. Well-defined MOFs can be constructed to improve conductivity, introduce active centers, and form carbon-based single-atom catalysts (SACs) with enhanced active sites that are accessible for the development of CO₂ conversion. In this review, the progress on pristine MOFs, MOF hybrids, and MOF-derived carbon-based SACs is summarized for the electrocatalytic reduction of CO₂. Finally, the limitations and potential improvement directions with respect to the advancement of MOF-related materials for the field of research are discussed. These summaries are expected to provide inspiration on reasonable design to develop stable and high-efficiency MOFs-based electrocatalysts for CO₂RR.