Methyl ethyl ketone ammoximation over Ti-MWW in a continuous slurry reactor

Song Zhao; Wei Xie; Yueming Liu; Peng Wu

doi:10.3724/SP.J.1088.2011.00735

Methyl ethyl ketone ammoximation over Ti-MWW in a continuous slurry reactor

Song Zhao
, Wei Xie
, Yueming Liu
, Peng Wu^*

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

8 引用（Scopus）

摘要

The catalytic performance of Ti-MWW/H₂O₂ system for the ammoximation of methyl ethyl ketone (MEK) to methyl ethyl ketone oxime (MEKO) was investigated in a continuous slurry reactor. The effects of various reaction parameters on the catalytic performance of Ti-MWW were studied in detail. Under the optimized reaction conditions, Ti-MWW showed MEK conversion and MEKO selectivity over 95% and 99%, respectively. Moreover, Ti-MWW can serve as an extremely robust catalyst, exhibiting a longer lifetime in comparison with conventional TS-1.

源语言	英语
页（从-至）	179-183
页数	5
期刊	Chinese Journal of Catalysis
卷	32
期	1
DOI	https://doi.org/10.3724/SP.J.1088.2011.00735
出版状态	已出版 - 1月 2011

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@article{8648a16639a843fba69103af7cda7922,

title = "Methyl ethyl ketone ammoximation over Ti-MWW in a continuous slurry reactor",

abstract = "The catalytic performance of Ti-MWW/H2O2 system for the ammoximation of methyl ethyl ketone (MEK) to methyl ethyl ketone oxime (MEKO) was investigated in a continuous slurry reactor. The effects of various reaction parameters on the catalytic performance of Ti-MWW were studied in detail. Under the optimized reaction conditions, Ti-MWW showed MEK conversion and MEKO selectivity over 95\% and 99\%, respectively. Moreover, Ti-MWW can serve as an extremely robust catalyst, exhibiting a longer lifetime in comparison with conventional TS-1.",

keywords = "Ammoximation, Hydrogen superoxide, Methyl ethyl ketone, Methyl ethyl ketone oxime, Slurry reactor, Ti-MWW zeolite",

author = "Song Zhao and Wei Xie and Yueming Liu and Peng Wu",

year = "2011",

month = jan,

doi = "10.3724/SP.J.1088.2011.00735",

language = "英语",

volume = "32",

pages = "179--183",

journal = "Chinese Journal of Catalysis",

issn = "1872-2067",

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TY - JOUR

T1 - Methyl ethyl ketone ammoximation over Ti-MWW in a continuous slurry reactor

AU - Zhao, Song

AU - Xie, Wei

AU - Liu, Yueming

AU - Wu, Peng

PY - 2011/1

Y1 - 2011/1

N2 - The catalytic performance of Ti-MWW/H2O2 system for the ammoximation of methyl ethyl ketone (MEK) to methyl ethyl ketone oxime (MEKO) was investigated in a continuous slurry reactor. The effects of various reaction parameters on the catalytic performance of Ti-MWW were studied in detail. Under the optimized reaction conditions, Ti-MWW showed MEK conversion and MEKO selectivity over 95% and 99%, respectively. Moreover, Ti-MWW can serve as an extremely robust catalyst, exhibiting a longer lifetime in comparison with conventional TS-1.

AB - The catalytic performance of Ti-MWW/H2O2 system for the ammoximation of methyl ethyl ketone (MEK) to methyl ethyl ketone oxime (MEKO) was investigated in a continuous slurry reactor. The effects of various reaction parameters on the catalytic performance of Ti-MWW were studied in detail. Under the optimized reaction conditions, Ti-MWW showed MEK conversion and MEKO selectivity over 95% and 99%, respectively. Moreover, Ti-MWW can serve as an extremely robust catalyst, exhibiting a longer lifetime in comparison with conventional TS-1.

KW - Ammoximation

KW - Hydrogen superoxide

KW - Methyl ethyl ketone

KW - Methyl ethyl ketone oxime

KW - Slurry reactor

KW - Ti-MWW zeolite

UR - https://www.scopus.com/pages/publications/79952796808

U2 - 10.3724/SP.J.1088.2011.00735

DO - 10.3724/SP.J.1088.2011.00735

M3 - 文章

AN - SCOPUS:79952796808

SN - 1872-2067

VL - 32

SP - 179

EP - 183

JO - Chinese Journal of Catalysis

JF - Chinese Journal of Catalysis

IS - 1

ER -

Methyl ethyl ketone ammoximation over Ti-MWW in a continuous slurry reactor

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