Iron porphyrin-catalyzed three-component reaction of ethyl diazoacetate with aliphatic amines and β,γ-unsaturated α-keto esters

Chaoqun Ma; Dong Xing; Changwei Zhai; Jiuwei Che; Shunying Liu; Jue Wang; Wenhao Hu

doi:10.1021/ol403011r

Iron porphyrin-catalyzed three-component reaction of ethyl diazoacetate with aliphatic amines and β,γ-unsaturated α-keto esters

Chaoqun Ma
, Dong Xing^*
, Changwei Zhai
, Jiuwei Che
, Shunying Liu
, Jue Wang
, Wenhao Hu

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

49 引用（Scopus）

摘要

An iron porphyrin-catalyzed three-component reaction of ethyl diazoacetate with aliphatic amines and β,γ-unsaturated α-keto esters is reported. The use of iron porphyrin catalyst allows aliphatic amines to be used as the substrate without encountering catalyst poisoning issue and a series of β-hydroxy-α-amino esters are produced in high yields with excellent regioselectivities.

源语言	英语
页（从-至）	6140-6143
页数	4
期刊	Organic Letters
卷	15
期	24
DOI	https://doi.org/10.1021/ol403011r
出版状态	已出版 - 20 12月 2013

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title = "Iron porphyrin-catalyzed three-component reaction of ethyl diazoacetate with aliphatic amines and β,γ-unsaturated α-keto esters",

abstract = "An iron porphyrin-catalyzed three-component reaction of ethyl diazoacetate with aliphatic amines and β,γ-unsaturated α-keto esters is reported. The use of iron porphyrin catalyst allows aliphatic amines to be used as the substrate without encountering catalyst poisoning issue and a series of β-hydroxy-α-amino esters are produced in high yields with excellent regioselectivities.",

author = "Chaoqun Ma and Dong Xing and Changwei Zhai and Jiuwei Che and Shunying Liu and Jue Wang and Wenhao Hu",

year = "2013",

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doi = "10.1021/ol403011r",

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T1 - Iron porphyrin-catalyzed three-component reaction of ethyl diazoacetate with aliphatic amines and β,γ-unsaturated α-keto esters

AU - Ma, Chaoqun

AU - Xing, Dong

AU - Zhai, Changwei

AU - Che, Jiuwei

AU - Liu, Shunying

AU - Wang, Jue

AU - Hu, Wenhao

PY - 2013/12/20

Y1 - 2013/12/20

N2 - An iron porphyrin-catalyzed three-component reaction of ethyl diazoacetate with aliphatic amines and β,γ-unsaturated α-keto esters is reported. The use of iron porphyrin catalyst allows aliphatic amines to be used as the substrate without encountering catalyst poisoning issue and a series of β-hydroxy-α-amino esters are produced in high yields with excellent regioselectivities.

AB - An iron porphyrin-catalyzed three-component reaction of ethyl diazoacetate with aliphatic amines and β,γ-unsaturated α-keto esters is reported. The use of iron porphyrin catalyst allows aliphatic amines to be used as the substrate without encountering catalyst poisoning issue and a series of β-hydroxy-α-amino esters are produced in high yields with excellent regioselectivities.

UR - https://www.scopus.com/pages/publications/84890905309

U2 - 10.1021/ol403011r

DO - 10.1021/ol403011r

M3 - 文章

AN - SCOPUS:84890905309

SN - 1523-7060

VL - 15

SP - 6140

EP - 6143

JO - Organic Letters

JF - Organic Letters

IS - 24

ER -

Iron porphyrin-catalyzed three-component reaction of ethyl diazoacetate with aliphatic amines and β,γ-unsaturated α-keto esters

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