Ionic manganese porphyrins with S-containing counter anions: Mimicking cytochrome P450 activity for alkene epoxidation

Yueqin Cai; Ye Liu; Yong Lu; Guohua Gao; Mingyuan He

doi:10.1007/s10562-008-9471-z

Ionic manganese porphyrins with S-containing counter anions: Mimicking cytochrome P450 activity for alkene epoxidation

Yueqin Cai
, Ye Liu^*
, Yong Lu
, Guohua Gao
, Mingyuan He

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

8 引用（Scopus）

摘要

The ionic manganese porphyrins, composed of trimethylbenzylammonium cations and S-containing anions, were designed to mimic cytochrome P450. S-containing anions could function as the stoichiometric axial ligands and counterions dually. Such ionic catalysts showed good catalytic performance in alkene epoxidation as compared with their neutral counterparts, in terms of activity, epoxide selectivity, and recyclability.

源语言	英语
页（从-至）	334-339
页数	6
期刊	Catalysis Letters
卷	124
期	3-4
DOI	https://doi.org/10.1007/s10562-008-9471-z
出版状态	已出版 - 8月 2008

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title = "Ionic manganese porphyrins with S-containing counter anions: Mimicking cytochrome P450 activity for alkene epoxidation",

abstract = "The ionic manganese porphyrins, composed of trimethylbenzylammonium cations and S-containing anions, were designed to mimic cytochrome P450. S-containing anions could function as the stoichiometric axial ligands and counterions dually. Such ionic catalysts showed good catalytic performance in alkene epoxidation as compared with their neutral counterparts, in terms of activity, epoxide selectivity, and recyclability.",

keywords = "Epoxidation, Ionic catalysts, Manganese porphyrins, Sulfur axial ligands",

author = "Yueqin Cai and Ye Liu and Yong Lu and Guohua Gao and Mingyuan He",

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doi = "10.1007/s10562-008-9471-z",

language = "英语",

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T2 - Mimicking cytochrome P450 activity for alkene epoxidation

AU - Cai, Yueqin

AU - Liu, Ye

AU - Lu, Yong

AU - Gao, Guohua

AU - He, Mingyuan

PY - 2008/8

Y1 - 2008/8

N2 - The ionic manganese porphyrins, composed of trimethylbenzylammonium cations and S-containing anions, were designed to mimic cytochrome P450. S-containing anions could function as the stoichiometric axial ligands and counterions dually. Such ionic catalysts showed good catalytic performance in alkene epoxidation as compared with their neutral counterparts, in terms of activity, epoxide selectivity, and recyclability.

AB - The ionic manganese porphyrins, composed of trimethylbenzylammonium cations and S-containing anions, were designed to mimic cytochrome P450. S-containing anions could function as the stoichiometric axial ligands and counterions dually. Such ionic catalysts showed good catalytic performance in alkene epoxidation as compared with their neutral counterparts, in terms of activity, epoxide selectivity, and recyclability.

KW - Epoxidation

KW - Ionic catalysts

KW - Manganese porphyrins

KW - Sulfur axial ligands

UR - https://www.scopus.com/pages/publications/49749136921

U2 - 10.1007/s10562-008-9471-z

DO - 10.1007/s10562-008-9471-z

M3 - 文章

AN - SCOPUS:49749136921

SN - 1011-372X

VL - 124

SP - 334

EP - 339

JO - Catalysis Letters

JF - Catalysis Letters

IS - 3-4

ER -

Ionic manganese porphyrins with S-containing counter anions: Mimicking cytochrome P450 activity for alkene epoxidation

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