Ionic conductor armored Li3V2(PO4)3: a robust electrode for lithium capture via capacitive desalination

Lanlan Han; Jiaqi Liu; Ruoxing Wang; Tianyi Wang; Chengyin Wang; Xingtao Xu; Likun Pan; Jiabao Li

doi:10.1039/d5cc03535j

Ionic conductor armored Li₃V₂(PO₄)₃: a robust electrode for lithium capture via capacitive desalination

Lanlan Han
, Jiaqi Liu
, Ruoxing Wang
, Tianyi Wang^*
, Chengyin Wang
, Xingtao Xu^*
, Likun Pan^*
, Jiabao Li^*

^*此作品的通讯作者

物理与电子科学学院

Yangzhou University
Zhejiang Ocean University

科研成果: 期刊稿件 › 文章 › 同行评审

3 引用（Scopus）

摘要

The poor ionic conductivity and sluggish interfacial kinetics of Li₃V₂(PO₄)₃ (LVP) severely limit its practical use for lithium extraction from brines. To overcome these limitations, we developed a robust amorphous Li₃PO₄ coating for LVP. This coating enhances ionic conductivity, accelerates interfacial kinetics, and improves structural stability. Consequently, the modified LVP achieves a high Li⁺ adsorption capacity of 6.48 mmol g⁻¹ within 150 mg L⁻¹ LiCl at 1.2 V with excellent selectivity in simulated brines.

源语言	英语
页（从-至）	14141-14144
页数	4
期刊	Chemical Communications
卷	61
期	74
DOI	https://doi.org/10.1039/d5cc03535j
出版状态	已出版 - 11 9月 2025

访问文件

10.1039/d5cc03535j

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{684b6409e5694e23bfb5c9a18c737567,

title = "Ionic conductor armored Li3V2(PO4)3: a robust electrode for lithium capture via capacitive desalination",

abstract = "The poor ionic conductivity and sluggish interfacial kinetics of Li3V2(PO4)3 (LVP) severely limit its practical use for lithium extraction from brines. To overcome these limitations, we developed a robust amorphous Li3PO4 coating for LVP. This coating enhances ionic conductivity, accelerates interfacial kinetics, and improves structural stability. Consequently, the modified LVP achieves a high Li+ adsorption capacity of 6.48 mmol g−1 within 150 mg L−1 LiCl at 1.2 V with excellent selectivity in simulated brines.",

author = "Lanlan Han and Jiaqi Liu and Ruoxing Wang and Tianyi Wang and Chengyin Wang and Xingtao Xu and Likun Pan and Jiabao Li",

note = "Publisher Copyright: {\textcopyright} 2025 The Royal Society of Chemistry.",

year = "2025",

month = sep,

day = "11",

doi = "10.1039/d5cc03535j",

language = "英语",

volume = "61",

pages = "14141--14144",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "74",

}

TY - JOUR

T1 - Ionic conductor armored Li3V2(PO4)3

T2 - a robust electrode for lithium capture via capacitive desalination

AU - Han, Lanlan

AU - Liu, Jiaqi

AU - Wang, Ruoxing

AU - Wang, Tianyi

AU - Wang, Chengyin

AU - Xu, Xingtao

AU - Pan, Likun

AU - Li, Jiabao

PY - 2025/9/11

Y1 - 2025/9/11

N2 - The poor ionic conductivity and sluggish interfacial kinetics of Li3V2(PO4)3 (LVP) severely limit its practical use for lithium extraction from brines. To overcome these limitations, we developed a robust amorphous Li3PO4 coating for LVP. This coating enhances ionic conductivity, accelerates interfacial kinetics, and improves structural stability. Consequently, the modified LVP achieves a high Li+ adsorption capacity of 6.48 mmol g−1 within 150 mg L−1 LiCl at 1.2 V with excellent selectivity in simulated brines.

AB - The poor ionic conductivity and sluggish interfacial kinetics of Li3V2(PO4)3 (LVP) severely limit its practical use for lithium extraction from brines. To overcome these limitations, we developed a robust amorphous Li3PO4 coating for LVP. This coating enhances ionic conductivity, accelerates interfacial kinetics, and improves structural stability. Consequently, the modified LVP achieves a high Li+ adsorption capacity of 6.48 mmol g−1 within 150 mg L−1 LiCl at 1.2 V with excellent selectivity in simulated brines.

UR - https://www.scopus.com/pages/publications/105015625080

U2 - 10.1039/d5cc03535j

DO - 10.1039/d5cc03535j

M3 - 文章

C2 - 40827863

AN - SCOPUS:105015625080

SN - 1359-7345

VL - 61

SP - 14141

EP - 14144

JO - Chemical Communications

JF - Chemical Communications

IS - 74

ER -

Ionic conductor armored Li3V2(PO4)3: a robust electrode for lithium capture via capacitive desalination

摘要

访问文件

其它文件与链接

指纹

引用此

Ionic conductor armored Li₃V₂(PO₄)₃: a robust electrode for lithium capture via capacitive desalination