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Intrinsic Features of an Ideal Glass

  • Deyan Sun
  • , Cheng Shang
  • , Zhipan Liu
  • , Xingao Gong*
  • *此作品的通讯作者
  • Fudan University
  • Collaborative Innovation Center of Advanced Microstructures

科研成果: 期刊稿件文章同行评审

摘要

In order to understand the long-standing problem of the nature of glass states, we perform intensive simulations on the thermodynamic properties and potential energy surface of an ideal glass. It is found that the atoms of an ideal glass manifest cooperative diffusion, and show clearly different behavior from the liquid state. By determining the potential energy surface, we demonstrate that the glass state has a flat potential landscape, which is the critical intrinsic feature of ideal glasses. When this potential region is accessible through any thermal or kinetic process, the glass state can be formed and a glass transition will occur, regardless of any special structural character. With this picture, the glass transition can be interpreted by the emergence of configurational entropies, as a consequence of flat potential landscapes.

源语言英语
文章编号026402
期刊Chinese Physics Letters
34
2
DOI
出版状态已出版 - 2017

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