Improving Efficiency and Reproducibility of Perovskite Solar Cells through Aggregation Control in Polyelectrolytes Hole Transport Layer

Xiaodong Li; Ying Chiao Wang; Liping Zhu; Wenjun Zhang; Hai Qiao Wang; Junfeng Fang

doi:10.1021/acsami.7b11977

Improving Efficiency and Reproducibility of Perovskite Solar Cells through Aggregation Control in Polyelectrolytes Hole Transport Layer

Xiaodong Li
, Ying Chiao Wang
, Liping Zhu
, Wenjun Zhang
, Hai Qiao Wang
, Junfeng Fang^*

^*此作品的通讯作者

CAS - Ningbo Institute of Material Technology and Engineering
University of Chinese Academy of Sciences

科研成果: 期刊稿件 › 文章 › 同行评审

97 引用（Scopus）

摘要

Here, we report that the performance of perovskite solar cells (PSCs) can be improved by aggregation control in polyelectrolytes interlayer. Through counterions tailoring and solvent optimization, the strong aggregation of polyelectrolytes P3CT-Na can be broken up by P3CT-CH₃NH₂. When using P3CT-CH₃NH₂ to replace P3CT-Na as hole transport layer, the average efficiency is greatly improved from 16.9 to 18.9% (highest 19.6%). Importantly, efficiency over 15% is obtained in 1 cm² devices with P3CT-CH₃NH₂, ∼50% higher than that with P3CT-Na (10.3%). Our work demonstrates the important role of aggregation control in polyelectrolytes interlayer, providing new opportunities to promote its application in PSCs.

源语言	英语
页（从-至）	31357-31361
页数	5
期刊	ACS Applied Materials and Interfaces
卷	9
期	37
DOI	https://doi.org/10.1021/acsami.7b11977
出版状态	已出版 - 20 9月 2017
已对外发布	是

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title = "Improving Efficiency and Reproducibility of Perovskite Solar Cells through Aggregation Control in Polyelectrolytes Hole Transport Layer",

abstract = "Here, we report that the performance of perovskite solar cells (PSCs) can be improved by aggregation control in polyelectrolytes interlayer. Through counterions tailoring and solvent optimization, the strong aggregation of polyelectrolytes P3CT-Na can be broken up by P3CT-CH3NH2. When using P3CT-CH3NH2 to replace P3CT-Na as hole transport layer, the average efficiency is greatly improved from 16.9 to 18.9\% (highest 19.6\%). Importantly, efficiency over 15\% is obtained in 1 cm2 devices with P3CT-CH3NH2, ∼50\% higher than that with P3CT-Na (10.3\%). Our work demonstrates the important role of aggregation control in polyelectrolytes interlayer, providing new opportunities to promote its application in PSCs.",

keywords = "aggregation control, counterions, hole transport layer, perovskite solar cells, polyelectrolytes",

author = "Xiaodong Li and Wang, \{Ying Chiao\} and Liping Zhu and Wenjun Zhang and Wang, \{Hai Qiao\} and Junfeng Fang",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

year = "2017",

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day = "20",

doi = "10.1021/acsami.7b11977",

language = "英语",

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T1 - Improving Efficiency and Reproducibility of Perovskite Solar Cells through Aggregation Control in Polyelectrolytes Hole Transport Layer

AU - Li, Xiaodong

AU - Wang, Ying Chiao

AU - Zhu, Liping

AU - Zhang, Wenjun

AU - Wang, Hai Qiao

AU - Fang, Junfeng

PY - 2017/9/20

Y1 - 2017/9/20

N2 - Here, we report that the performance of perovskite solar cells (PSCs) can be improved by aggregation control in polyelectrolytes interlayer. Through counterions tailoring and solvent optimization, the strong aggregation of polyelectrolytes P3CT-Na can be broken up by P3CT-CH3NH2. When using P3CT-CH3NH2 to replace P3CT-Na as hole transport layer, the average efficiency is greatly improved from 16.9 to 18.9% (highest 19.6%). Importantly, efficiency over 15% is obtained in 1 cm2 devices with P3CT-CH3NH2, ∼50% higher than that with P3CT-Na (10.3%). Our work demonstrates the important role of aggregation control in polyelectrolytes interlayer, providing new opportunities to promote its application in PSCs.

AB - Here, we report that the performance of perovskite solar cells (PSCs) can be improved by aggregation control in polyelectrolytes interlayer. Through counterions tailoring and solvent optimization, the strong aggregation of polyelectrolytes P3CT-Na can be broken up by P3CT-CH3NH2. When using P3CT-CH3NH2 to replace P3CT-Na as hole transport layer, the average efficiency is greatly improved from 16.9 to 18.9% (highest 19.6%). Importantly, efficiency over 15% is obtained in 1 cm2 devices with P3CT-CH3NH2, ∼50% higher than that with P3CT-Na (10.3%). Our work demonstrates the important role of aggregation control in polyelectrolytes interlayer, providing new opportunities to promote its application in PSCs.

KW - aggregation control

KW - counterions

KW - hole transport layer

KW - perovskite solar cells

KW - polyelectrolytes

UR - https://www.scopus.com/pages/publications/85029750626

U2 - 10.1021/acsami.7b11977

DO - 10.1021/acsami.7b11977

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SN - 1944-8244

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EP - 31361

JO - ACS Applied Materials and Interfaces

JF - ACS Applied Materials and Interfaces

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ER -

Improving Efficiency and Reproducibility of Perovskite Solar Cells through Aggregation Control in Polyelectrolytes Hole Transport Layer

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