Improved photocatalytic activity of g-C₃N₄ derived from cyanamide-urea solution

This paper describes the fabrication of g-C₃N₄ by the polymerization of cyanamide-urea solution at elevated temperatures. The textural properties and electronic band structure of the obtained g-C₃N₄ were investigated in detail. The photocatalytic activity for both oxidative and reductive reactions of the as-synthesized g-C₃N₄ was found to be enhanced as the polymerization temperature increase and the g-C₃N₄ obtained at 700°C (CN-700) showed the best photocatalytic activity under visible-light (λ > 420 nm). Considering that the rather wide band gap (3.01 eV) of CN-700 disables the electron transition from the valence band to the conduction band by visible light (λ > 420 nm), it is believed the n-π∗ transition, which is alternatively proposed in this study, plays a key role in its photocatalytic activity. In light of this discovery, the variation of the electron-transition mechanism for g-C₃N₄ fabricated at different polymerization temperatures has been firstly investigated.