Highly Regioselective Radical Transformation of N-Sulfonyl-1,2,3-triazoles in Air

Zi Li; Qinghua Wei; Longlong Song; Wangyujing Han; Xiang Wu; Yun Zhao; Fei Xia; Shunying Liu

doi:10.1021/acs.orglett.9b02269

Highly Regioselective Radical Transformation of N-Sulfonyl-1,2,3-triazoles in Air

Zi Li
, Qinghua Wei
, Longlong Song
, Wangyujing Han
, Xiang Wu
, Yun Zhao
, Fei Xia^*
, Shunying Liu

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

40 引用（Scopus）

摘要

The classic transformations of N-sulfonyl-1,2,3-triazoles were processed via nitrogen anion (hydrolysis, etc.) and carbene intermediates, and no efficient examples via radical intermediates were developed. Here, we reported a catalyst-free radical chain transformation of N-sulfonyl-1,2,3-triazoles to access an intermolecular oxidative C(sp³)-H coupling to yield N²-selective products in air without any catalysts.

源语言	英语
页（从-至）	6413-6417
页数	5
期刊	Organic Letters
卷	21
期	16
DOI	https://doi.org/10.1021/acs.orglett.9b02269
出版状态	已出版 - 16 8月 2019

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abstract = "The classic transformations of N-sulfonyl-1,2,3-triazoles were processed via nitrogen anion (hydrolysis, etc.) and carbene intermediates, and no efficient examples via radical intermediates were developed. Here, we reported a catalyst-free radical chain transformation of N-sulfonyl-1,2,3-triazoles to access an intermolecular oxidative C(sp3)-H coupling to yield N2-selective products in air without any catalysts.",

author = "Zi Li and Qinghua Wei and Longlong Song and Wangyujing Han and Xiang Wu and Yun Zhao and Fei Xia and Shunying Liu",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

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T1 - Highly Regioselective Radical Transformation of N-Sulfonyl-1,2,3-triazoles in Air

AU - Li, Zi

AU - Wei, Qinghua

AU - Song, Longlong

AU - Han, Wangyujing

AU - Wu, Xiang

AU - Zhao, Yun

AU - Xia, Fei

AU - Liu, Shunying

PY - 2019/8/16

Y1 - 2019/8/16

N2 - The classic transformations of N-sulfonyl-1,2,3-triazoles were processed via nitrogen anion (hydrolysis, etc.) and carbene intermediates, and no efficient examples via radical intermediates were developed. Here, we reported a catalyst-free radical chain transformation of N-sulfonyl-1,2,3-triazoles to access an intermolecular oxidative C(sp3)-H coupling to yield N2-selective products in air without any catalysts.

AB - The classic transformations of N-sulfonyl-1,2,3-triazoles were processed via nitrogen anion (hydrolysis, etc.) and carbene intermediates, and no efficient examples via radical intermediates were developed. Here, we reported a catalyst-free radical chain transformation of N-sulfonyl-1,2,3-triazoles to access an intermolecular oxidative C(sp3)-H coupling to yield N2-selective products in air without any catalysts.

UR - https://www.scopus.com/pages/publications/85070712285

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DO - 10.1021/acs.orglett.9b02269

M3 - 文章

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AN - SCOPUS:85070712285

SN - 1523-7060

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SP - 6413

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JO - Organic Letters

JF - Organic Letters

IS - 16

ER -

Highly Regioselective Radical Transformation of N-Sulfonyl-1,2,3-triazoles in Air

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