Highly efficient synthesis of mixed 3,3′-bisindoles via Rh(II)-catalyzed three-component reaction of 3-diazooxindoles with indoles and ethyl glyoxylate

Dong Xing; Changcheng Jing; Xinfeng Li; Huang Qiu; Wenhao Hu

doi:10.1021/ol401414w

Highly efficient synthesis of mixed 3,3′-bisindoles via Rh(II)-catalyzed three-component reaction of 3-diazooxindoles with indoles and ethyl glyoxylate

Dong Xing^*
, Changcheng Jing
, Xinfeng Li
, Huang Qiu
, Wenhao Hu

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

54 引用（Scopus）

摘要

A series of mixed 3,3′-bisindoles were efficiently synthesized via a Rh₂(OAc)₄-catalyzed three-component reaction of 3-diazooxindoles with indoles and ethyl glyoxylate in high yields with excellent diastereoselectivities. The product easily underwent further synthetic transformations and could be potentially applied to the total synthesis of (±)-gliocladin C and related natural alkaloids.

源语言	英语
页（从-至）	3578-3581
页数	4
期刊	Organic Letters
卷	15
期	14
DOI	https://doi.org/10.1021/ol401414w
出版状态	已出版 - 19 7月 2013

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abstract = "A series of mixed 3,3′-bisindoles were efficiently synthesized via a Rh2(OAc)4-catalyzed three-component reaction of 3-diazooxindoles with indoles and ethyl glyoxylate in high yields with excellent diastereoselectivities. The product easily underwent further synthetic transformations and could be potentially applied to the total synthesis of (±)-gliocladin C and related natural alkaloids.",

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T1 - Highly efficient synthesis of mixed 3,3′-bisindoles via Rh(II)-catalyzed three-component reaction of 3-diazooxindoles with indoles and ethyl glyoxylate

AU - Xing, Dong

AU - Jing, Changcheng

AU - Li, Xinfeng

AU - Qiu, Huang

AU - Hu, Wenhao

PY - 2013/7/19

Y1 - 2013/7/19

N2 - A series of mixed 3,3′-bisindoles were efficiently synthesized via a Rh2(OAc)4-catalyzed three-component reaction of 3-diazooxindoles with indoles and ethyl glyoxylate in high yields with excellent diastereoselectivities. The product easily underwent further synthetic transformations and could be potentially applied to the total synthesis of (±)-gliocladin C and related natural alkaloids.

AB - A series of mixed 3,3′-bisindoles were efficiently synthesized via a Rh2(OAc)4-catalyzed three-component reaction of 3-diazooxindoles with indoles and ethyl glyoxylate in high yields with excellent diastereoselectivities. The product easily underwent further synthetic transformations and could be potentially applied to the total synthesis of (±)-gliocladin C and related natural alkaloids.

UR - https://www.scopus.com/pages/publications/84880518774

U2 - 10.1021/ol401414w

DO - 10.1021/ol401414w

M3 - 文章

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AN - SCOPUS:84880518774

SN - 1523-7060

VL - 15

SP - 3578

EP - 3581

JO - Organic Letters

JF - Organic Letters

IS - 14

ER -

Highly efficient synthesis of mixed 3,3′-bisindoles via Rh(II)-catalyzed three-component reaction of 3-diazooxindoles with indoles and ethyl glyoxylate

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