跳到主要导航 跳到搜索 跳到主要内容

Highly efficient epoxidation of propylene over a novel Ti-MWW catalyst

科研成果: 书/报告/会议事项章节章节同行评审

摘要

The liquid-phase epoxidation of propylene with H2O2 has been carried out over novel Ti-MWW catalysts to produce propylene oxide (PO) actively and selectively. Ti-MWW showed a superior catalytic activity to conventional TS-1. Furthermore, Ti-MWW preferred an aprotic solvent of acetonitrile in which the solvolysis of PO was suppressed effectively to a negligible level. Ti-MWW thus was capable of showing a PO selectivity as high as 99%. The most suitable solvent for TS-1 was protic methanol in which propylene glycol and its monomethyl ethers were co-produced.

源语言英语
主期刊名From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference
出版商Elsevier Inc.
1236-1243
页数8
版本B
ISBN(印刷版)0444530681, 9780444530684
DOI
出版状态已出版 - 2007

出版系列

姓名Studies in Surface Science and Catalysis
编号B
170
ISSN(印刷版)0167-2991

指纹

探究 'Highly efficient epoxidation of propylene over a novel Ti-MWW catalyst' 的科研主题。它们共同构成独一无二的指纹。

引用此