Growth of Cu 2ZnSn(S,Se) 4 thin films by a simple eco-friendly solution route method

H. Zhang; Z. Q. Li; Y. R. Chen; J. J. Li; Z. Sun; Z. Yang; S. M. Huang

doi:10.1142/S0218625X12500345

Growth of Cu ₂ZnSn(S,Se) ₄ thin films by a simple eco-friendly solution route method

H. Zhang
, Z. Q. Li
, Y. R. Chen
, J. J. Li
, Z. Sun
, Z. Yang
, S. M. Huang^*

^*此作品的通讯作者

物理与电子科学学院

East China Normal University
Shanghai Jiao Tong University

科研成果: 期刊稿件 › 文献综述 › 同行评审

5 引用（Scopus）

摘要

A simple and hydrazine-free solution-based approach for depositing Cu ₂ZnSnS ₄ (CZTS) and Cu ₂ZnSn(S,Se) ₄ (CZTSSe) absorber layers is reported. The process involves incorporating metal salts (Cu(CH ₃COO) ₂, Zn(CH ₃COO) ₂, SnCl ₂) and thiourea into a single pyridine-based solution, spin-coating a precursor film, and sulfurizing with sulfur powders or selenizing using Se pellets in an inert atmosphere, to form the desired CZTS or CZTSSe films. X-ray diffraction and Raman spectra studies show that kesterite CZTS and CZTSSe are formed after sulfurization and selenization, respectively. The selenized CZTSSe displays higher crystallinity than the sulfurized CZTS. Photovoltaic devices (glass/Mo/CZTSSe/CdS/i-ZnO/n-ZnO/A) employing the solution precursor selenized at 500°C have yielded power conversion efficiency of 1.44% under AM 1.5 illumination.

源语言	英语
文章编号	1250034
期刊	Surface Review and Letters
卷	19
期	4
DOI	https://doi.org/10.1142/S0218625X12500345
出版状态	已出版 - 8月 2012

联合国可持续发展目标

此成果有助于实现下列可持续发展目标：

可持续发展目标 7 经济适用的清洁能源
可持续发展目标 13 气候行动

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10.1142/S0218625X12500345

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链接到 Scopus 的出版物

引用此

@article{7145967fe7a543538e50f415156772c9,

title = "Growth of Cu 2ZnSn(S,Se) 4 thin films by a simple eco-friendly solution route method",

abstract = "A simple and hydrazine-free solution-based approach for depositing Cu 2ZnSnS 4 (CZTS) and Cu 2ZnSn(S,Se) 4 (CZTSSe) absorber layers is reported. The process involves incorporating metal salts (Cu(CH 3COO) 2, Zn(CH 3COO) 2, SnCl 2) and thiourea into a single pyridine-based solution, spin-coating a precursor film, and sulfurizing with sulfur powders or selenizing using Se pellets in an inert atmosphere, to form the desired CZTS or CZTSSe films. X-ray diffraction and Raman spectra studies show that kesterite CZTS and CZTSSe are formed after sulfurization and selenization, respectively. The selenized CZTSSe displays higher crystallinity than the sulfurized CZTS. Photovoltaic devices (glass/Mo/CZTSSe/CdS/i-ZnO/n-ZnO/A) employing the solution precursor selenized at 500°C have yielded power conversion efficiency of 1.44\% under AM 1.5 illumination.",

keywords = "Cu ZnSn(S,Se), selenization, solution, sulfurization, thin film solar cells",

author = "H. Zhang and Li, \{Z. Q.\} and Chen, \{Y. R.\} and Li, \{J. J.\} and Z. Sun and Z. Yang and Huang, \{S. M.\}",

year = "2012",

month = aug,

doi = "10.1142/S0218625X12500345",

language = "英语",

volume = "19",

journal = "Surface Review and Letters",

issn = "0218-625X",

publisher = "World Scientific Publishing Co. Pte Ltd",

number = "4",

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TY - JOUR

T1 - Growth of Cu 2ZnSn(S,Se) 4 thin films by a simple eco-friendly solution route method

AU - Zhang, H.

AU - Li, Z. Q.

AU - Chen, Y. R.

AU - Li, J. J.

AU - Sun, Z.

AU - Yang, Z.

AU - Huang, S. M.

PY - 2012/8

Y1 - 2012/8

N2 - A simple and hydrazine-free solution-based approach for depositing Cu 2ZnSnS 4 (CZTS) and Cu 2ZnSn(S,Se) 4 (CZTSSe) absorber layers is reported. The process involves incorporating metal salts (Cu(CH 3COO) 2, Zn(CH 3COO) 2, SnCl 2) and thiourea into a single pyridine-based solution, spin-coating a precursor film, and sulfurizing with sulfur powders or selenizing using Se pellets in an inert atmosphere, to form the desired CZTS or CZTSSe films. X-ray diffraction and Raman spectra studies show that kesterite CZTS and CZTSSe are formed after sulfurization and selenization, respectively. The selenized CZTSSe displays higher crystallinity than the sulfurized CZTS. Photovoltaic devices (glass/Mo/CZTSSe/CdS/i-ZnO/n-ZnO/A) employing the solution precursor selenized at 500°C have yielded power conversion efficiency of 1.44% under AM 1.5 illumination.

AB - A simple and hydrazine-free solution-based approach for depositing Cu 2ZnSnS 4 (CZTS) and Cu 2ZnSn(S,Se) 4 (CZTSSe) absorber layers is reported. The process involves incorporating metal salts (Cu(CH 3COO) 2, Zn(CH 3COO) 2, SnCl 2) and thiourea into a single pyridine-based solution, spin-coating a precursor film, and sulfurizing with sulfur powders or selenizing using Se pellets in an inert atmosphere, to form the desired CZTS or CZTSSe films. X-ray diffraction and Raman spectra studies show that kesterite CZTS and CZTSSe are formed after sulfurization and selenization, respectively. The selenized CZTSSe displays higher crystallinity than the sulfurized CZTS. Photovoltaic devices (glass/Mo/CZTSSe/CdS/i-ZnO/n-ZnO/A) employing the solution precursor selenized at 500°C have yielded power conversion efficiency of 1.44% under AM 1.5 illumination.

KW - Cu ZnSn(S,Se)

KW - selenization

KW - solution

KW - sulfurization

KW - thin film solar cells

UR - https://www.scopus.com/pages/publications/84864751752

U2 - 10.1142/S0218625X12500345

DO - 10.1142/S0218625X12500345

M3 - 文献综述

AN - SCOPUS:84864751752

SN - 0218-625X

VL - 19

JO - Surface Review and Letters

JF - Surface Review and Letters

IS - 4

M1 - 1250034

ER -

Growth of Cu 2ZnSn(S,Se) 4 thin films by a simple eco-friendly solution route method

摘要

联合国可持续发展目标

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Growth of Cu ₂ZnSn(S,Se) ₄ thin films by a simple eco-friendly solution route method