Gold-catalyzed efficient synthesis of 2,4-disubstituted furans from aryloxy-enynes

Ende Li; Wenjun Yao; Xin Xie; Chengyu Wang; Yushang Shao; Yanzhong Li

doi:10.1039/c2ob07173h

Gold-catalyzed efficient synthesis of 2,4-disubstituted furans from aryloxy-enynes

Ende Li
, Wenjun Yao
, Xin Xie
, Chengyu Wang
, Yushang Shao
, Yanzhong Li^*

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

36 引用（Scopus）

摘要

A series of (E)-1-aryloxy-1-en-3-ynes has been prepared by Sonogashira coupling of 2-bromo-3-aryloxypropenoates with terminal alkynes using Pd(PPh ₃) ₄ and CuI as the catalysts in Et ₃N. The resulting enynyl-aryl ethers are found to be highly applicable to the synthesis of 2,4-disubstituted furans with an ester group at C-4 position through an Au/Ag-catalyzed annulation reaction under extremely mild reaction conditions.

源语言	英语
页（从-至）	2960-2965
页数	6
期刊	Organic and Biomolecular Chemistry
卷	10
期	15
DOI	https://doi.org/10.1039/c2ob07173h
出版状态	已出版 - 21 4月 2012

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title = "Gold-catalyzed efficient synthesis of 2,4-disubstituted furans from aryloxy-enynes",

abstract = "A series of (E)-1-aryloxy-1-en-3-ynes has been prepared by Sonogashira coupling of 2-bromo-3-aryloxypropenoates with terminal alkynes using Pd(PPh 3) 4 and CuI as the catalysts in Et 3N. The resulting enynyl-aryl ethers are found to be highly applicable to the synthesis of 2,4-disubstituted furans with an ester group at C-4 position through an Au/Ag-catalyzed annulation reaction under extremely mild reaction conditions.",

author = "Ende Li and Wenjun Yao and Xin Xie and Chengyu Wang and Yushang Shao and Yanzhong Li",

year = "2012",

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doi = "10.1039/c2ob07173h",

language = "英语",

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T1 - Gold-catalyzed efficient synthesis of 2,4-disubstituted furans from aryloxy-enynes

AU - Li, Ende

AU - Yao, Wenjun

AU - Xie, Xin

AU - Wang, Chengyu

AU - Shao, Yushang

AU - Li, Yanzhong

PY - 2012/4/21

Y1 - 2012/4/21

N2 - A series of (E)-1-aryloxy-1-en-3-ynes has been prepared by Sonogashira coupling of 2-bromo-3-aryloxypropenoates with terminal alkynes using Pd(PPh 3) 4 and CuI as the catalysts in Et 3N. The resulting enynyl-aryl ethers are found to be highly applicable to the synthesis of 2,4-disubstituted furans with an ester group at C-4 position through an Au/Ag-catalyzed annulation reaction under extremely mild reaction conditions.

AB - A series of (E)-1-aryloxy-1-en-3-ynes has been prepared by Sonogashira coupling of 2-bromo-3-aryloxypropenoates with terminal alkynes using Pd(PPh 3) 4 and CuI as the catalysts in Et 3N. The resulting enynyl-aryl ethers are found to be highly applicable to the synthesis of 2,4-disubstituted furans with an ester group at C-4 position through an Au/Ag-catalyzed annulation reaction under extremely mild reaction conditions.

UR - https://www.scopus.com/pages/publications/84858981517

U2 - 10.1039/c2ob07173h

DO - 10.1039/c2ob07173h

M3 - 文章

C2 - 22402590

AN - SCOPUS:84858981517

SN - 1477-0520

VL - 10

SP - 2960

EP - 2965

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 15

ER -

Gold-catalyzed efficient synthesis of 2,4-disubstituted furans from aryloxy-enynes

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