Geometry directed self-selection in the coordination-driven self-assembly of irregular supramolecular polygons

Yao Rong Zheng; Brian H. Northrop; Hai Bo Yang; Liang Zhao; Peter J. Stang

doi:10.1021/jo9002932

Geometry directed self-selection in the coordination-driven self-assembly of irregular supramolecular polygons

Yao Rong Zheng
, Brian H. Northrop
, Hai Bo Yang
, Liang Zhao
, Peter J. Stang

化学与分子工程学院

University of Utah

科研成果: 期刊稿件 › 文章 › 同行评审

37 引用（Scopus）

摘要

The self-assembly of irregular metallo-supramolecular hexagons and parallelograms has been achieved in a self-selective manner upon mixing 120° unsymmetrical dipyridyl ligands with 60° or 120° organoplatinum acceptors in a 1:1 ratio. The polygons have been characterized using ³¹P and ¹H multinuclear NMR spectroscopy and electrospray ionization mass spectrometry (ESI-MS) as well as X-ray crystallography. Geometric features of the molecular subunits direct the self-selection process, which is supported by molecular force field computations.

源语言	英语
页（从-至）	3554-3557
页数	4
期刊	Journal of Organic Chemistry
卷	74
期	9
DOI	https://doi.org/10.1021/jo9002932
出版状态	已出版 - 1 5月 2009

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10.1021/jo9002932

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abstract = "The self-assembly of irregular metallo-supramolecular hexagons and parallelograms has been achieved in a self-selective manner upon mixing 120° unsymmetrical dipyridyl ligands with 60° or 120° organoplatinum acceptors in a 1:1 ratio. The polygons have been characterized using 31P and 1H multinuclear NMR spectroscopy and electrospray ionization mass spectrometry (ESI-MS) as well as X-ray crystallography. Geometric features of the molecular subunits direct the self-selection process, which is supported by molecular force field computations.",

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AU - Zheng, Yao Rong

AU - Northrop, Brian H.

AU - Yang, Hai Bo

AU - Zhao, Liang

AU - Stang, Peter J.

PY - 2009/5/1

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N2 - The self-assembly of irregular metallo-supramolecular hexagons and parallelograms has been achieved in a self-selective manner upon mixing 120° unsymmetrical dipyridyl ligands with 60° or 120° organoplatinum acceptors in a 1:1 ratio. The polygons have been characterized using 31P and 1H multinuclear NMR spectroscopy and electrospray ionization mass spectrometry (ESI-MS) as well as X-ray crystallography. Geometric features of the molecular subunits direct the self-selection process, which is supported by molecular force field computations.

AB - The self-assembly of irregular metallo-supramolecular hexagons and parallelograms has been achieved in a self-selective manner upon mixing 120° unsymmetrical dipyridyl ligands with 60° or 120° organoplatinum acceptors in a 1:1 ratio. The polygons have been characterized using 31P and 1H multinuclear NMR spectroscopy and electrospray ionization mass spectrometry (ESI-MS) as well as X-ray crystallography. Geometric features of the molecular subunits direct the self-selection process, which is supported by molecular force field computations.

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JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 9

ER -

Geometry directed self-selection in the coordination-driven self-assembly of irregular supramolecular polygons

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