Fabrication of nanotubules and microspheres from the self-assembly of amphiphilic monochain stearic acid derivatives

Lidong Zhang; Haiqing Li; Chang Sik Ha; Hongsuk Suh; Il Kim

doi:10.1021/la103480p

Fabrication of nanotubules and microspheres from the self-assembly of amphiphilic monochain stearic acid derivatives

Lidong Zhang
, Haiqing Li
, Chang Sik Ha
, Hongsuk Suh
, Il Kim^*

^*此作品的通讯作者

Pusan National University

科研成果: 期刊稿件 › 文章 › 同行评审

18 引用（Scopus）

摘要

A series of amphiphilic monochain derivatives of stearic acid, CH ₃(CH₂)₁₆CONH(CH₂)_nNH ₂ (n = 2, 3, 4, 6), CH₃(CH₂) ₁₆CONH(CH₂)₂S₂(CH₂) ₂NH₂, and [CH₃(CH₂) ₁₆CONH]₂(CH₂)₂, are synthesized, and their self-assembly behaviors have been investigated in 1,2-dichloroethane (DCE). In addition to the concentration of the compound in DCE, the number of methylene units in hydrophilic segments play a crucial role in determining the final morphology of self-assembling structures from nanotubules with 20 nm inner diameter to microspheres with an average diameter of 20 μm. The external texture of the microsphere is also influenced by the number of methylene units in the hydrophilic segment. The microspheres formed by highly ordered aggregattion of nanobelts show high thermal stability. The particular processes and causations have been expatiated.

源语言	英语
页（从-至）	17890-17895
页数	6
期刊	Langmuir
卷	26
期	23
DOI	https://doi.org/10.1021/la103480p
出版状态	已出版 - 7 12月 2010
已对外发布	是

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title = "Fabrication of nanotubules and microspheres from the self-assembly of amphiphilic monochain stearic acid derivatives",

abstract = "A series of amphiphilic monochain derivatives of stearic acid, CH 3(CH2)16CONH(CH2)nNH 2 (n = 2, 3, 4, 6), CH3(CH2) 16CONH(CH2)2S2(CH2) 2NH2, and [CH3(CH2) 16CONH]2(CH2)2, are synthesized, and their self-assembly behaviors have been investigated in 1,2-dichloroethane (DCE). In addition to the concentration of the compound in DCE, the number of methylene units in hydrophilic segments play a crucial role in determining the final morphology of self-assembling structures from nanotubules with 20 nm inner diameter to microspheres with an average diameter of 20 μm. The external texture of the microsphere is also influenced by the number of methylene units in the hydrophilic segment. The microspheres formed by highly ordered aggregattion of nanobelts show high thermal stability. The particular processes and causations have been expatiated.",

author = "Lidong Zhang and Haiqing Li and Ha, \{Chang Sik\} and Hongsuk Suh and Il Kim",

year = "2010",

month = dec,

day = "7",

doi = "10.1021/la103480p",

language = "英语",

volume = "26",

pages = "17890--17895",

journal = "Langmuir",

issn = "0743-7463",

publisher = "American Chemical Society",

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T1 - Fabrication of nanotubules and microspheres from the self-assembly of amphiphilic monochain stearic acid derivatives

AU - Zhang, Lidong

AU - Li, Haiqing

AU - Ha, Chang Sik

AU - Suh, Hongsuk

AU - Kim, Il

PY - 2010/12/7

Y1 - 2010/12/7

N2 - A series of amphiphilic monochain derivatives of stearic acid, CH 3(CH2)16CONH(CH2)nNH 2 (n = 2, 3, 4, 6), CH3(CH2) 16CONH(CH2)2S2(CH2) 2NH2, and [CH3(CH2) 16CONH]2(CH2)2, are synthesized, and their self-assembly behaviors have been investigated in 1,2-dichloroethane (DCE). In addition to the concentration of the compound in DCE, the number of methylene units in hydrophilic segments play a crucial role in determining the final morphology of self-assembling structures from nanotubules with 20 nm inner diameter to microspheres with an average diameter of 20 μm. The external texture of the microsphere is also influenced by the number of methylene units in the hydrophilic segment. The microspheres formed by highly ordered aggregattion of nanobelts show high thermal stability. The particular processes and causations have been expatiated.

AB - A series of amphiphilic monochain derivatives of stearic acid, CH 3(CH2)16CONH(CH2)nNH 2 (n = 2, 3, 4, 6), CH3(CH2) 16CONH(CH2)2S2(CH2) 2NH2, and [CH3(CH2) 16CONH]2(CH2)2, are synthesized, and their self-assembly behaviors have been investigated in 1,2-dichloroethane (DCE). In addition to the concentration of the compound in DCE, the number of methylene units in hydrophilic segments play a crucial role in determining the final morphology of self-assembling structures from nanotubules with 20 nm inner diameter to microspheres with an average diameter of 20 μm. The external texture of the microsphere is also influenced by the number of methylene units in the hydrophilic segment. The microspheres formed by highly ordered aggregattion of nanobelts show high thermal stability. The particular processes and causations have been expatiated.

UR - https://www.scopus.com/pages/publications/78650241021

U2 - 10.1021/la103480p

DO - 10.1021/la103480p

M3 - 文章

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AN - SCOPUS:78650241021

SN - 0743-7463

VL - 26

SP - 17890

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JO - Langmuir

JF - Langmuir

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ER -

Fabrication of nanotubules and microspheres from the self-assembly of amphiphilic monochain stearic acid derivatives

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