Epoxidations catalyzed by an ionic manganese(III) porphyrin and characterization of manganese(V, IV)-oxo porphyrin complexes by UV-vis spectrophotometer in ionic liquid solution

Hong Jiao Zhang; Ye Liu; Yong Lu; Xiao Shuang He; Xia Wang; Xia Ding

doi:10.1016/j.molcata.2008.03.001

Epoxidations catalyzed by an ionic manganese(III) porphyrin and characterization of manganese(V, IV)-oxo porphyrin complexes by UV-vis spectrophotometer in ionic liquid solution

Hong Jiao Zhang
, Ye Liu^*
, Yong Lu
, Xiao Shuang He
, Xia Wang
, Xia Ding

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

27 引用（Scopus）

摘要

An ionic metalloporphyrin of manganese tetrakis-(4-N-trimethylaminophenyl)porphyrin hexafluorophosphate ([Mn^IIITTMAPP][PF₆]₅, 1c), resided in the mixed ionic liquids (ILs) of [BzMIM]BF₄ and [BMIM]BF₄, proved to be an efficient and recyclable catalytic system for styrene (derivative) epoxidations without the involvement of the auxiliary axial ligands. The epoxidation rate in 1c-IL could be dramatically promoted by addition of water. In the built-up 1c-IL-H₂O system, the active manganese(V)-oxo porphyrin intermediate (1d, 444 nm) was stabilized to facilitate its detection by a UV-vis spectrophotometer. And the formation of the μ-oxo Mn(IV) porphyrin dimer (1e, 416 nm) was completely suppressed due to the counteraction between 1c and the IL.

源语言	英语
页（从-至）	80-86
页数	7
期刊	Journal of Molecular Catalysis A: Chemical
卷	287
期	1-2
DOI	https://doi.org/10.1016/j.molcata.2008.03.001
出版状态	已出版 - 15 5月 2008

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@article{43fa8229c32449d582c59051c3b1cab2,

title = "Epoxidations catalyzed by an ionic manganese(III) porphyrin and characterization of manganese(V, IV)-oxo porphyrin complexes by UV-vis spectrophotometer in ionic liquid solution",

abstract = "An ionic metalloporphyrin of manganese tetrakis-(4-N-trimethylaminophenyl)porphyrin hexafluorophosphate ([MnIIITTMAPP][PF6]5, 1c), resided in the mixed ionic liquids (ILs) of [BzMIM]BF4 and [BMIM]BF4, proved to be an efficient and recyclable catalytic system for styrene (derivative) epoxidations without the involvement of the auxiliary axial ligands. The epoxidation rate in 1c-IL could be dramatically promoted by addition of water. In the built-up 1c-IL-H2O system, the active manganese(V)-oxo porphyrin intermediate (1d, 444 nm) was stabilized to facilitate its detection by a UV-vis spectrophotometer. And the formation of the μ-oxo Mn(IV) porphyrin dimer (1e, 416 nm) was completely suppressed due to the counteraction between 1c and the IL.",

keywords = "Epoxidation, Ionic liquids, Manganese porphyrins, UV-vis spectrophotometer",

author = "Zhang, \{Hong Jiao\} and Ye Liu and Yong Lu and He, \{Xiao Shuang\} and Xia Wang and Xia Ding",

year = "2008",

month = may,

day = "15",

doi = "10.1016/j.molcata.2008.03.001",

language = "英语",

volume = "287",

pages = "80--86",

journal = "Journal of Molecular Catalysis A: Chemical",

issn = "1381-1169",

publisher = "Elsevier B.V.",

number = "1-2",

}

Epoxidations catalyzed by an ionic manganese(III) porphyrin and characterization of manganese(V, IV)-oxo porphyrin complexes by UV-vis spectrophotometer in ionic liquid solution. / Zhang, Hong Jiao; Liu, Ye ; Lu, Yong 等.
在: Journal of Molecular Catalysis A: Chemical, 卷 287, 号码 1-2, 15.05.2008, 页码 80-86.

科研成果: 期刊稿件 › 文章 › 同行评审

TY - JOUR

T1 - Epoxidations catalyzed by an ionic manganese(III) porphyrin and characterization of manganese(V, IV)-oxo porphyrin complexes by UV-vis spectrophotometer in ionic liquid solution

AU - Zhang, Hong Jiao

AU - Liu, Ye

AU - Lu, Yong

AU - He, Xiao Shuang

AU - Wang, Xia

AU - Ding, Xia

PY - 2008/5/15

Y1 - 2008/5/15

N2 - An ionic metalloporphyrin of manganese tetrakis-(4-N-trimethylaminophenyl)porphyrin hexafluorophosphate ([MnIIITTMAPP][PF6]5, 1c), resided in the mixed ionic liquids (ILs) of [BzMIM]BF4 and [BMIM]BF4, proved to be an efficient and recyclable catalytic system for styrene (derivative) epoxidations without the involvement of the auxiliary axial ligands. The epoxidation rate in 1c-IL could be dramatically promoted by addition of water. In the built-up 1c-IL-H2O system, the active manganese(V)-oxo porphyrin intermediate (1d, 444 nm) was stabilized to facilitate its detection by a UV-vis spectrophotometer. And the formation of the μ-oxo Mn(IV) porphyrin dimer (1e, 416 nm) was completely suppressed due to the counteraction between 1c and the IL.

AB - An ionic metalloporphyrin of manganese tetrakis-(4-N-trimethylaminophenyl)porphyrin hexafluorophosphate ([MnIIITTMAPP][PF6]5, 1c), resided in the mixed ionic liquids (ILs) of [BzMIM]BF4 and [BMIM]BF4, proved to be an efficient and recyclable catalytic system for styrene (derivative) epoxidations without the involvement of the auxiliary axial ligands. The epoxidation rate in 1c-IL could be dramatically promoted by addition of water. In the built-up 1c-IL-H2O system, the active manganese(V)-oxo porphyrin intermediate (1d, 444 nm) was stabilized to facilitate its detection by a UV-vis spectrophotometer. And the formation of the μ-oxo Mn(IV) porphyrin dimer (1e, 416 nm) was completely suppressed due to the counteraction between 1c and the IL.

KW - Epoxidation

KW - Ionic liquids

KW - Manganese porphyrins

KW - UV-vis spectrophotometer

UR - https://www.scopus.com/pages/publications/43549116560

U2 - 10.1016/j.molcata.2008.03.001

DO - 10.1016/j.molcata.2008.03.001

M3 - 文章

AN - SCOPUS:43549116560

SN - 1381-1169

VL - 287

SP - 80

EP - 86

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

IS - 1-2

ER -

Epoxidations catalyzed by an ionic manganese(III) porphyrin and characterization of manganese(V, IV)-oxo porphyrin complexes by UV-vis spectrophotometer in ionic liquid solution

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