Epoxidation of Various Functionalized Olefins by a Ti-MWW/H2O2 Catalytic System

Ningning LI; Yueming LIU; Haihong WU; Xiaohong LI; Wei XIE; Zhonglin ZHAO; Peng WU; Mingyuan HE

doi:10.1016/S1872-2067(08)60018-2

Epoxidation of Various Functionalized Olefins by a Ti-MWW/H₂O₂ Catalytic System

Ningning LI
, Yueming LIU
, Haihong WU
, Xiaohong LI
, Wei XIE
, Zhonglin ZHAO
, Peng WU^*
, Mingyuan HE

^*此作品的通讯作者

化学与分子工程学院

East China Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

6 引用（Scopus）

摘要

The catalytic properties of Ti-MWW catalysts for the epoxidation of olefins with different functional groups using hydrogen peroxide as an oxidant were studied. Ti-MWW shows higher olefin conversion and epoxide selectivity than the conventional titanosilicate TS-1. Solvents influence the catalytic activity of Ti-MWW, and water is the best one in the epoxidation of ethyl acrylate and allyl acetate. The functional groups with high electrophilicity and adjacent to the C=C bonds retard the catalytic activity for olefin epoxidation.

源语言	英语
页（从-至）	102-104
页数	3
期刊	Chinese Journal of Catalysis
卷	29
期	2
DOI	https://doi.org/10.1016/S1872-2067(08)60018-2
出版状态	已出版 - 2月 2008

访问文件

10.1016/S1872-2067(08)60018-2

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{d66b8129eb5446cb9549d02bddd92698,

title = "Epoxidation of Various Functionalized Olefins by a Ti-MWW/H2O2 Catalytic System",

abstract = "The catalytic properties of Ti-MWW catalysts for the epoxidation of olefins with different functional groups using hydrogen peroxide as an oxidant were studied. Ti-MWW shows higher olefin conversion and epoxide selectivity than the conventional titanosilicate TS-1. Solvents influence the catalytic activity of Ti-MWW, and water is the best one in the epoxidation of ethyl acrylate and allyl acetate. The functional groups with high electrophilicity and adjacent to the C=C bonds retard the catalytic activity for olefin epoxidation.",

keywords = "TS-1, Ti-MWW, epoxidation, functionalized olefin",

author = "Ningning LI and Yueming LIU and Haihong WU and Xiaohong LI and Wei XIE and Zhonglin ZHAO and Peng WU and Mingyuan HE",

year = "2008",

month = feb,

doi = "10.1016/S1872-2067(08)60018-2",

language = "英语",

volume = "29",

pages = "102--104",

journal = "Chinese Journal of Catalysis",

issn = "1872-2067",

publisher = "Science Press ",

number = "2",

}

TY - JOUR

T1 - Epoxidation of Various Functionalized Olefins by a Ti-MWW/H2O2 Catalytic System

AU - LI, Ningning

AU - LIU, Yueming

AU - WU, Haihong

AU - LI, Xiaohong

AU - XIE, Wei

AU - ZHAO, Zhonglin

AU - WU, Peng

AU - HE, Mingyuan

PY - 2008/2

Y1 - 2008/2

N2 - The catalytic properties of Ti-MWW catalysts for the epoxidation of olefins with different functional groups using hydrogen peroxide as an oxidant were studied. Ti-MWW shows higher olefin conversion and epoxide selectivity than the conventional titanosilicate TS-1. Solvents influence the catalytic activity of Ti-MWW, and water is the best one in the epoxidation of ethyl acrylate and allyl acetate. The functional groups with high electrophilicity and adjacent to the C=C bonds retard the catalytic activity for olefin epoxidation.

AB - The catalytic properties of Ti-MWW catalysts for the epoxidation of olefins with different functional groups using hydrogen peroxide as an oxidant were studied. Ti-MWW shows higher olefin conversion and epoxide selectivity than the conventional titanosilicate TS-1. Solvents influence the catalytic activity of Ti-MWW, and water is the best one in the epoxidation of ethyl acrylate and allyl acetate. The functional groups with high electrophilicity and adjacent to the C=C bonds retard the catalytic activity for olefin epoxidation.

KW - TS-1

KW - Ti-MWW

KW - epoxidation

KW - functionalized olefin

UR - https://www.scopus.com/pages/publications/40949113603

U2 - 10.1016/S1872-2067(08)60018-2

DO - 10.1016/S1872-2067(08)60018-2

M3 - 文章

AN - SCOPUS:40949113603

SN - 1872-2067

VL - 29

SP - 102

EP - 104

JO - Chinese Journal of Catalysis

JF - Chinese Journal of Catalysis

IS - 2

ER -

Epoxidation of Various Functionalized Olefins by a Ti-MWW/H2O2 Catalytic System

摘要

访问文件

其它文件与链接

学术指纹

引用此

Epoxidation of Various Functionalized Olefins by a Ti-MWW/H₂O₂ Catalytic System