Enhanced photochemical formation of secondary organic aerosols during the COVID-19 lockdown in Northern China

To eliminate the spread of a novel coronavirus breaking out in the end of 2019 (COVID-19), the Chinese government has implemented a nationwide lockdown policy after the Chinese lunar New Year of 2020, resulting in a sharp reduction in air pollutant emissions. To investigate the impact of the lockdown on aerosol chemistry, the number fraction, size distribution and formation process of oxalic acid (C₂) containing particles and its precursors were studied using a single particle aerosol mass spectrometer (SPAMS) at the urban site of Liaocheng in the North China Plain (NCP). Our results showed that five air pollutants (i.e., PM_2.5, PM₁₀, SO₂, NO₂, and CO) decreased by 30.0–59.8% during the lockdown compared to those before the lockdown, while O₃ increased by 63.9% during the lockdown mainly due to the inefficient titration effect of O₃ via NO reduction. The increased O₃ concentration can boost the atmospheric oxidizing capacity and further enhance the formation of secondary organic aerosols, thereby significantly enhancing the C₂ particles and its precursors as observed during the lockdown. Before the lockdown, C₂ particles were significantly originated from biomass burning emissions and their subsequent aqueous-phase oxidation. The hourly variation patterns and correlation analysis before the lockdown suggested that relative humidity (RH) and aerosol liquid water content (ALWC) played a key role in the formation of C₂ particles and the increased aerosol acidity can promote the conversion of precursors such as glyoxal (Gly) and methyglyoxal (mGly) into C₂ particles in the aqueous phase. RH and ALWC decreased sharply but O₃ concentration and solar radiation increased remarkably during the lockdown, the O₃-dominated photochemical pathways played an important role in the formation of C₂ particles in which aerosol acidity was ineffective. Our study indicated that air pollution treatment sponges on a joint-control and balanced strategy for controlling numerous pollutants.