Enantioselective transformation of allyl carbonates into branched allyl carbamates by using amines and recycling CO2 under iridium catalysis

Sheng Cai Zheng; Min Zhang; Xiao Ming Zhao

doi:10.1002/chem.201402388

Enantioselective transformation of allyl carbonates into branched allyl carbamates by using amines and recycling CO₂ under iridium catalysis

Sheng Cai Zheng
, Min Zhang
, Xiao Ming Zhao^*

^*此作品的通讯作者

Tongji University

科研成果: 期刊稿件 › 文章 › 同行评审

27 引用（Scopus）

摘要

Enantioselective transformation of allyl carbonates into branched allyl carbamates by using amines and recycling CO₂ in the presence of an Ir complex and K₃PO₄ was accomplished. This provided branched allyl carbamates in fair to excellent yields with up to 98:2 regioselectivity and 93% ee. The role of CO₂ in this transformation is discussed as well.

源语言	英语
页（从-至）	7216-7221
页数	6
期刊	Chemistry - A European Journal
卷	20
期	24
DOI	https://doi.org/10.1002/chem.201402388
出版状态	已出版 - 10 6月 2014
已对外发布	是

访问文件

10.1002/chem.201402388

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{ee16d4c734eb44ecbed34f5407110ad3,

title = "Enantioselective transformation of allyl carbonates into branched allyl carbamates by using amines and recycling CO2 under iridium catalysis",

abstract = "Enantioselective transformation of allyl carbonates into branched allyl carbamates by using amines and recycling CO2 in the presence of an Ir complex and K3PO4 was accomplished. This provided branched allyl carbamates in fair to excellent yields with up to 98:2 regioselectivity and 93\% ee. The role of CO2 in this transformation is discussed as well.",

keywords = "allylcarbamates, carbon dioxide, domino reactions, enantioselectivity, iridium",

author = "Zheng, \{Sheng Cai\} and Min Zhang and Zhao, \{Xiao Ming\}",

year = "2014",

month = jun,

day = "10",

doi = "10.1002/chem.201402388",

language = "英语",

volume = "20",

pages = "7216--7221",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "John Wiley and Sons Inc",

number = "24",

}

TY - JOUR

T1 - Enantioselective transformation of allyl carbonates into branched allyl carbamates by using amines and recycling CO2 under iridium catalysis

AU - Zheng, Sheng Cai

AU - Zhang, Min

AU - Zhao, Xiao Ming

PY - 2014/6/10

Y1 - 2014/6/10

N2 - Enantioselective transformation of allyl carbonates into branched allyl carbamates by using amines and recycling CO2 in the presence of an Ir complex and K3PO4 was accomplished. This provided branched allyl carbamates in fair to excellent yields with up to 98:2 regioselectivity and 93% ee. The role of CO2 in this transformation is discussed as well.

AB - Enantioselective transformation of allyl carbonates into branched allyl carbamates by using amines and recycling CO2 in the presence of an Ir complex and K3PO4 was accomplished. This provided branched allyl carbamates in fair to excellent yields with up to 98:2 regioselectivity and 93% ee. The role of CO2 in this transformation is discussed as well.

KW - allylcarbamates

KW - carbon dioxide

KW - domino reactions

KW - enantioselectivity

KW - iridium

UR - https://www.scopus.com/pages/publications/84902139420

U2 - 10.1002/chem.201402388

DO - 10.1002/chem.201402388

M3 - 文章

AN - SCOPUS:84902139420

SN - 0947-6539

VL - 20

SP - 7216

EP - 7221

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 24

ER -

Enantioselective transformation of allyl carbonates into branched allyl carbamates by using amines and recycling CO2 under iridium catalysis

摘要

访问文件

其它文件与链接

指纹

引用此

Enantioselective transformation of allyl carbonates into branched allyl carbamates by using amines and recycling CO₂ under iridium catalysis